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全面分析污泥调理过程中屈服应力与脱水性能的关系:来自各种处理方法的见解。

Comprehensive analysis of the relationship between yield stress and dewatering performance in sludge conditioning: Insights from various treatment methods.

机构信息

Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou, 350002, China; Center of Wastewater Resource Reuse, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou, Fujian, 350002, China.

Fujian Provincial Key Laboratory of Soil Environmental Health and Regulation, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou, 350002, China; Center of Wastewater Resource Reuse, College of Resources and Environment, Fujian Agriculture and Forestry University, Fuzhou, Fujian, 350002, China.

出版信息

Chemosphere. 2024 Oct;365:143377. doi: 10.1016/j.chemosphere.2024.143377. Epub 2024 Sep 19.

Abstract

Understanding the relationship between sludge yield stress (σ) and dewatering performance is essential for optimizing sludge conditioning processes. This study systematically investigates the effects of various conditioning methods-including thermal hydrolysis (TH), freezing/thawing (FT), anaerobic digestion (AD), polyaluminum chloride (PAC), polyacrylamide (PAM), and Fenton treatment (Fenton)-on sludge yield stress and its correlation with dewatering efficiency. Using linear regression, partial least squares regression (PLSR), and correlation heatmap analyses, we reveal significant variations in the correlation between σ and dewatering indexes, including moisture content (Mc), capillary suction time (CST), and bound water proportion (Wb/Wt), depending on the conditioning method and intensity. Under FT and PAM conditioning, σ shows a strong negative linear correlation with dewatering performance, with Pearson's r values exceeding -0.880, indicating that a decrease in σ corresponds to improved dewatering efficiency. Conversely, AD conditioning exhibits a positive linear correlation, with r values up to 0.993, suggesting that an increase in σ correlates with reduced dewatering efficiency. For TH, PAC, and Fenton treatments, the correlation between σ and dewatering metrics is highly sensitive to changes in treatment intensity. In the PLSR analysis, the VIP values, which quantify the importance of each predictor variable, indicate that Wb/Wt in TH conditioning (VIP = 1.649) and CST in PAC (VIP = 1.309) and Fenton (VIP = 1.299) conditioning strongly influence σ. This study highlights the significant impact of conditioning methods and intensities on the correlation between σ and dewatering performance. While σ provides valuable insights as a predictive indicator, its predictive power is limited in more complex conditioning scenarios. Therefore, optimizing conditioning intensity and incorporating multiple rheological parameters are essential for achieving superior sludge dewatering outcomes.

摘要

了解污泥屈服应力(σ)与脱水性能之间的关系对于优化污泥调理过程至关重要。本研究系统研究了各种调理方法——包括热水解(TH)、冷冻/解冻(FT)、厌氧消化(AD)、聚合氯化铝(PAC)、聚丙烯酰胺(PAM)和芬顿处理(Fenton)——对污泥屈服应力及其与脱水效率的相关性的影响。通过线性回归、偏最小二乘回归(PLSR)和相关热图分析,我们揭示了在不同调理方法和强度下,σ与脱水指标之间的相关性存在显著变化。FT 和 PAM 调理条件下,σ与脱水性能呈强负线性相关,皮尔逊 r 值超过-0.880,表明σ的降低对应着脱水效率的提高。相反,AD 调理条件下呈正线性相关,r 值高达 0.993,表明σ的增加与脱水效率的降低相关。TH、PAC 和 Fenton 处理条件下,σ与脱水指标之间的相关性对处理强度的变化非常敏感。在 PLSR 分析中,重要性变量(VIP)值量化了每个预测变量的重要性,表明 TH 调理中 Wb/Wt(VIP=1.649)和 PAC 及 Fenton 调理中 CST(VIP=1.309 和 1.299)对σ的影响较大。本研究强调了调理方法和强度对σ与脱水性能之间相关性的重要影响。虽然σ作为预测指标提供了有价值的见解,但在更复杂的调理场景中,其预测能力有限。因此,优化调理强度并结合多个流变学参数对于实现卓越的污泥脱水效果至关重要。

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