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推进抗生素检测与降解:石墨相氮化碳(g-CN)应用的最新创新。

Advancing antibiotic detection and degradation: recent innovations in graphitic carbon nitride (g-CN) applications.

机构信息

Center of Pharmaceutical Engineering and Technology, Harbin University of Commerce, Harbin 150076, China.

Center of Pharmaceutical Engineering and Technology, Harbin University of Commerce, Harbin 150076, China.

出版信息

J Environ Sci (China). 2025 Apr;150:657-675. doi: 10.1016/j.jes.2024.03.033. Epub 2024 Apr 3.

Abstract

The uncontrolled release of antibiotics into the environment would be extremely harmful to human health and ecosystems. Therefore, it is in urgent need to monitor the environment and promote the detection and degradation of antibiotics to the relatively harmless by-products to a feasible extent. Graphitic carbon nitride (g-CN) is a non-metallic n-type semiconductor that can be used for the antibiotic detection and degradation due to its easy synthesis process, excellent chemical stability and unique optical properties. Unfortunately, the utilization of visible light, electron-hole recombination and electron conductivity have hindered its potential applications in the fields of photocatalytic degradation and electrochemical detection. Although previous publications have highlighted the diverse modification methods for the g-CN-based materials, the underlying structure-performance relationships of g-CN, especially for the detection and degradation of antibiotics, remains to be further explored. In view of this, the current review centered on the recent progress in the modification techniques of g-CN, the detection and degradation of antibiotics using the g-CN-based materials, as well as the potential antibiotic degradation mechanisms of the g-CN-based materials. Additionally, the underlying applications of the g-CN-based materials for antibiotic detection and degradation were also prospected. This review would provide a valuable research foundation and the up-to-date information for the g-CN-based materials to combat antibiotic pollution in the environment.

摘要

抗生素被无节制地排放到环境中,会对人类健康和生态系统造成极大的危害。因此,迫切需要监测环境,并在可行的程度上促进抗生素的检测和降解,以使其转化为相对无害的副产物。石墨相氮化碳(g-CN)是一种非金属 n 型半导体,由于其合成工艺简单、化学稳定性好和独特的光学性质,可用于抗生素的检测和降解。然而,可见光的利用、电子-空穴复合和电子电导率等问题,限制了其在光催化降解和电化学检测等领域的潜在应用。尽管之前的出版物强调了 g-CN 基材料的多种改性方法,但 g-CN 的结构-性能关系,尤其是其在抗生素检测和降解方面的应用,仍有待进一步探索。有鉴于此,本综述重点介绍了 g-CN 的改性技术、g-CN 基材料在抗生素检测和降解方面的应用,以及 g-CN 基材料潜在的抗生素降解机制。此外,还展望了 g-CN 基材料在抗生素检测和降解方面的应用前景。本综述将为 g-CN 基材料对抗生素污染的环境提供有价值的研究基础和最新信息。

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