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多相催化对实现资源效率和循环经济的贡献。

Contributions of heterogeneous catalysis enabling resource efficiency and circular economy.

作者信息

Mürtz Sonja D, Palkovits Regina

机构信息

RWTH Aachen University, Institute for Technical and Macromolecular Chemistry, Worringerweg 2 , Aachen 52074, Germany.

Forschungszentrum Jülich, Institute for a Sustainable Hydrogen Economy, Marie-Curie-Str. 5 , Jülich 52428, Germany.

出版信息

Philos Trans A Math Phys Eng Sci. 2024 Nov 9;382(2282):20230264. doi: 10.1098/rsta.2023.0264. Epub 2024 Sep 23.

DOI:10.1098/rsta.2023.0264
PMID:39307160
Abstract

Our industry today is predominantly based on linear value chains. Raw materials are extracted from primary sources, processed into products, used, and disposed of at the end of their life cycle. This linear economy causes a wide range of negative environmental impacts owing to the resulting greenhouse gas emissions and pollution of marine and terrestrial ecosystems. Closed carbon cycles and climate-neutral energy production are essential for the production not only of fuels but also of all chemicals, including plastics and fertilizers, to counteract climate change and further damage to the environment. In this regard, this article discusses the importance of heterogeneous catalysts for selected technologies associated with this transformation of the resource base and energy supply. It discusses the technological framework conditions of a net CO-neutral industry, with a focus on electrocatalytic water-splitting for hydrogen production, as well as the catalytic challenges of production of chemicals for the whole value chain using biomass, CO and plastic waste as raw materials. This article is part of the discussion meeting issue 'Green carbon for the chemical industry of the future'.

摘要

如今,我们的行业主要基于线性价值链。原材料从主要来源提取,加工成产品,使用后在其生命周期结束时进行处理。这种线性经济由于产生的温室气体排放以及对海洋和陆地生态系统的污染,造成了广泛的负面环境影响。封闭的碳循环和气候中和的能源生产对于不仅燃料而且包括塑料和肥料在内的所有化学品的生产都是必不可少的,以应对气候变化和对环境的进一步破坏。在这方面,本文讨论了非均相催化剂对于与资源基础和能源供应这种转变相关的选定技术的重要性。它讨论了净二氧化碳中和行业的技术框架条件,重点是用于制氢的电催化水分解,以及使用生物质、一氧化碳和塑料废物作为原材料在整个价值链中生产化学品的催化挑战。本文是“未来化学工业的绿色碳”讨论会议题的一部分。

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