Department of Chemistry, Amrita Vishwa Vidyapeetham, Amritapuri, Kollam, Kerala, India.
Department of Chemistry, Indian Institute of Space Science and Technology, Valiyamala PO, Kerala, India.
Int J Biol Macromol. 2024 Nov;280(Pt 2):135887. doi: 10.1016/j.ijbiomac.2024.135887. Epub 2024 Sep 20.
Lignin, a valuable biomaterial having an array of exciting properties is increasingly favoured as a reinforcement material in the fabrication of green composites. Reinforcement in biopolymers like natural rubber (NR) using lignin nanoparticles (LNP) is considered a hotspot today. In this study, LNP synthesized via the homogenization method was incorporated into natural rubber latex (NRL) using probe sonication, and NR/Lignin nanocomposites (NR/LNP) were fabricated using latex dipping method. The addition of LNP resulted in significant enhancements in mechanical and antibacterial properties, biodegradability, and ultraviolet (UV) blocking capabilities with the addition of 7 parts per hundred rubber (phr) of LNP, due to the uniform dispersion and effective interaction between NR and LNP. This research demonstrates a versatile pathway for integrating LNP into NR through a green method, enabling the production of eco-friendly NR nanocomposites for multifunctional applications. This pathway contributes to a safe disposal of NR based products.
木质素是一种具有多种令人兴奋特性的有价值的生物材料,作为一种增强材料,它在绿色复合材料的制造中越来越受欢迎。在天然橡胶(NR)等生物聚合物中使用木质素纳米颗粒(LNP)进行增强被认为是当今的一个热点。在这项研究中,通过均化法合成的 LNP 通过探针超声处理被掺入天然橡胶胶乳(NRL)中,并且使用胶乳浸渍法制备 NR/木质素纳米复合材料(NR/LNP)。由于 NR 和 LNP 之间的均匀分散和有效相互作用,添加 LNP 导致机械和抗菌性能、生物降解性和紫外线(UV)阻挡能力显著提高,添加 7 份每百橡胶(phr)的 LNP 后,由于 NR 和 LNP 之间的均匀分散和有效相互作用。这项研究通过绿色方法展示了将 LNP 整合到 NR 中的多功能途径,为多功能应用生产环保 NR 纳米复合材料。这种方法有助于安全处理基于 NR 的产品。