通过铜（II）促进的光氧化还原过程全合成双环马汉宁碱。
Total synthesis of bicyclomahanimbine by Cu(ii)-promoted photoredox process.
作者信息
Dangar Shilpa, Roy Tiyasa, Noskar Suman, Bisai Alakesh
机构信息
Indian Institute of Science Education and Research Kolkata Mohanpur, Nadia West Bengal 741246 India
Department of Chemistry, Indian Institute of Science Education and Research Bhopal Bhauri Bhopal 462 066 Madhya Pradesh India.
出版信息
RSC Adv. 2024 Sep 23;14(41):30110-30115. doi: 10.1039/d4ra05863a. eCollection 2024 Sep 18.
Since the isolation of carbazole alkaloids, the synthetic chemists have witnessed an upsurge in research of them due to their potential pharmacological properties. Our approach shows the total syntheses of five such biorelevant pyrano-[3,2]-carbazole alkaloids, emphasizing biomimetic and innovative synthetic methodologies such as cascade reactions and strategic bond formations through sustainable electrochemical and photochemical conditions.
自从咔唑生物碱被分离出来后，由于其潜在的药理特性，合成化学家们见证了对它们的研究热潮。我们的方法展示了五种此类与生物相关的吡喃并-[3,2]-咔唑生物碱的全合成，强调了仿生和创新的合成方法，如级联反应以及通过可持续的电化学和光化学条件进行的策略性键形成。
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