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用于电化学能源应用的单金属/双金属掺杂及异质结构工程

Mono-/Bimetallic Doped and Heterostructure Engineering for Electrochemical Energy Applications.

作者信息

Chu Dawei, Liang Zhongwang, Cheng Yi, Chai Dong-Feng, Li Meijia

机构信息

College of Energy Engineering, Huanghuai University, Zhumadian, 463000, China.

College of Chemistry and Chemical Engineering, Qiqihar University, Qiqihar, 161006, China.

出版信息

ChemSusChem. 2025 Feb 1;18(3):e202401435. doi: 10.1002/cssc.202401435. Epub 2024 Nov 5.

DOI:10.1002/cssc.202401435
PMID:39321338
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11790008/
Abstract

Designing efficient materials is crucial to meeting specific requirements in various electrochemical energy applications. Mono-/bimetallic doped and heterostructure engineering have attracted considerable research interest due to their unique functionalities and potential for electrochemical energy conversion and storage. However, addressing material imperfections such as low conductivity and poor active sites requires a strategic approach to design. This review explores the latest advancements in materials modified by mono-/bimetallic doped and heterojunction strategies for electrochemical energy applications. It can be subdivided into three key points: (i) the regulatory mechanisms of metal doping and heterostructure engineering for materials; (ii) the preparation methods of materials with various engineering strategies; and (iii) the synergistic effects of two engineering approaches, further highlighting their applications in supercapacitors, alkaline ion batteries, and electrocatalysis. Finally, the review concludes with perspectives and recommendations for further research to advance these technologies.

摘要

设计高效材料对于满足各种电化学能源应用中的特定要求至关重要。单金属/双金属掺杂和异质结构工程因其独特的功能以及在电化学能量转换和存储方面的潜力而引起了相当大的研究兴趣。然而，解决诸如低导电性和活性位点不足等材料缺陷需要一种战略性的设计方法。本综述探讨了通过单金属/双金属掺杂和异质结策略改性的材料在电化学能源应用方面的最新进展。它可细分为三个关键点：(i) 材料的金属掺杂和异质结构工程的调控机制；(ii) 采用各种工程策略制备材料的方法；(iii) 两种工程方法的协同效应，进一步突出它们在超级电容器、碱性离子电池和电催化中的应用。最后，综述以推进这些技术的进一步研究的观点和建议作为结尾。

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