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利用二氧化钛(TiO)纳米颗粒改善棉织物的功能和机械性能。

Utilization of titanium dioxide (TiO) nanoparticles to improve functionality and mechanical performances of cotton fabric.

作者信息

Tania Imana Shahrin, Ali Mohammad

机构信息

Department of Mechanical Engineering, Bangladesh University of Engineering and Technology, Dhaka-1000, Bangladesh.

Department of Wet Process Engineering, Bangladesh University of Textiles, Dhaka-1208, Bangladesh.

出版信息

Heliyon. 2024 Sep 14;10(18):e37899. doi: 10.1016/j.heliyon.2024.e37899. eCollection 2024 Sep 30.

Abstract

This study aims to produce high-quality functional cotton fabric through the deposition of nano TiO. Here nanoparticles are deposited by the pad-dry-cure method with different recipes formulated using an acrylic binder and wax emulsifier together with TiO nanoparticles to observe the optimal effect on the final quality. The treated fabric is characterized by SEM, EDS, XRD, and FTIR. To analyze the results, the antimicrobial properties, UV protection, and crease resistance are measured as functional properties. Furthermore, tensile and tearing strength, frictional resistance, bending length, abrasion resistance, and pilling are determined as mechanical properties. The results confirm that the binder significantly affects on nano deposition and improves the mentioned functional characteristics. However, the deposition of nano TiO has deteriorated cotton's mechanical properties, and that degradation is intensified by the use of binder. This degradation problem is overcome by using the emulsifier as an auxiliary since the recipe having an emulsifier improves all the mechanical qualities of nano-treated cotton fabric. Particularly, the sample containing a binder and an emulsifier (Nano TiO-3) ensures up to 97 % UV-ray blockage, 93 % antibacterial activity, and 9 % increase in tensile strength.

摘要

本研究旨在通过纳米二氧化钛的沉积制备高质量的功能性棉织物。在此,采用轧染-烘干-焙烘法,使用丙烯酸粘合剂和蜡乳化剂与纳米二氧化钛配制不同配方来沉积纳米颗粒,以观察其对最终质量的最佳效果。通过扫描电子显微镜(SEM)、能谱仪(EDS)、X射线衍射仪(XRD)和傅里叶变换红外光谱仪(FTIR)对处理后的织物进行表征。为分析结果,将抗菌性能、紫外线防护性能和抗皱性能作为功能特性进行测定。此外,将拉伸强度、撕裂强度、摩擦阻力、弯曲长度、耐磨性和起球性能确定为机械性能。结果证实,粘合剂对纳米颗粒的沉积有显著影响,并改善了上述功能特性。然而,纳米二氧化钛的沉积使棉的机械性能下降,且粘合剂的使用加剧了这种降解。通过使用乳化剂作为助剂克服了这一降解问题,因为含有乳化剂的配方改善了纳米处理棉织物的所有机械性能。特别是,含有粘合剂和乳化剂的样品(纳米二氧化钛-3)可确保高达97%的紫外线阻隔率、93%的抗菌活性以及9%的拉伸强度增幅。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5dc4/11422557/5fbb92eb80d2/gr1.jpg

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