Henan Institute of Science and Technology, Xinxiang 453003, China.
J Agric Food Chem. 2024 Oct 9;72(40):21959-21972. doi: 10.1021/acs.jafc.4c04537. Epub 2024 Sep 27.
Pesticides are extensively utilized in contemporary agriculture to manage pests, enhance crop yields, and sustain productivity. Nevertheless, the persistent herbicide represents a dual-edged weapon. On one hand, their prolonged efficacy enables reduced application frequency during crop growth seasons, resulting in cost savings on labor. However, the presence of these residues within fields poses safety risks to soil quality, sensitive crops in subsequent rotations, agricultural product quality, and the ecological environment. This review presents a comprehensive review on the mechanisms of action, application risks, ecotoxicology, and residue analysis methods of nine representative persistent herbicides (namely, atrazine, imazethapyr, imazapic, mesosulfuron-methyl, halosulfuron-methyl, fomesafen, diflufenican, quinclorac, and pyroxasulfone). The objective is to guide their scientific and rational utilization in agricultural practices while minimizing phytotoxicity risks and effectively monitoring and controlling soil pollution. These can not only provide practical recommendations for mitigating potential plant toxicity and ecological environmental risks but also contribute valuable technical insights for efficient soil pollution monitoring and prevention. Additionally, unaddressed research objectives were also anticipated.
农药在现代农业中被广泛应用于防治害虫、提高作物产量和维持生产力。然而,持久性除草剂是一把双刃剑。一方面,它们的长期效果使得在作物生长季节减少了应用频率,从而节省了劳动力成本。然而,这些残留物在田间的存在对土壤质量、后续轮作中的敏感作物、农产品质量和生态环境构成了安全风险。本综述全面介绍了九种代表性持久性除草剂(即莠去津、咪草烟、咪唑烟酸、甲磺隆、甲磺隆、乙羧氟草醚、氟磺胺草醚、二氟吡隆、氯喹喔啉和吡唑磺草酮)的作用机制、应用风险、生态毒理学和残留分析方法。目的是指导它们在农业实践中的科学合理利用,同时最大限度地降低植物毒性风险,并有效地监测和控制土壤污染。这不仅为减轻潜在的植物毒性和生态环境风险提供了实用建议,也为高效的土壤污染监测和防治提供了有价值的技术见解。此外,还预计了未解决的研究目标。