Nagy Katalin, Iacob Bogdan-Cezar, Bodoki Ede, Oprean Radu
Analytical Chemistry Department, "Iuliu Hațieganu" University of Medicine and Pharmacy, 4, Louis Pasteur St., 400349 Cluj-Napoca, Romania.
Foods. 2024 Sep 19;13(18):2961. doi: 10.3390/foods13182961.
This study investigates the thermal stability of omega fatty acid-enriched vegetable oils, focusing on their behavior under high-temperature conditions commonly encountered during frying. This research aims to evaluate changes in fatty acid composition, particularly the degradation of essential omega-3, -6, and -9 fatty acids, and the formation of harmful compounds such as trans fatty acids (TFAs). Various commercially available vegetable oils labeled as containing omega-3, omega-6, and omega-9, including refined sunflower, high-oleic sunflower, rapeseed, and blends, were analyzed under temperatures from 180 °C to 230 °C for varying durations. The fatty acid profiles were determined using gas chromatography-mass spectrometry (GC-MS). The results indicated a significant degradation of polyunsaturated fatty acids (PUFAs) and an increase in saturated fatty acids (SFAs) and TFAs with prolonged heating. The findings highlight the varying degrees of thermal stability among different oils, with high-oleic sunflower and blended oils exhibiting greater resistance to thermal degradation compared to conventional sunflower oils. This study underscores the importance of selecting oils with favorable fatty acid compositions for high-temperature cooking to minimize adverse health effects associated with degraded oil consumption. Furthermore, it provides insights into optimizing oil blends to enhance thermal stability and maintain nutritional quality, crucial for consumer health and food industry practices.
本研究调查了富含欧米伽脂肪酸的植物油的热稳定性,重点关注其在油炸过程中常见的高温条件下的行为。本研究旨在评估脂肪酸组成的变化,特别是必需的欧米伽-3、-6和-9脂肪酸的降解,以及反式脂肪酸(TFA)等有害化合物的形成。对各种市售的标注含有欧米伽-3、欧米伽-6和欧米伽-9的植物油进行了分析,这些植物油包括精炼向日葵油、高油酸向日葵油、菜籽油以及混合油,在180℃至230℃的温度下加热不同时长。使用气相色谱-质谱联用仪(GC-MS)测定脂肪酸谱。结果表明,随着加热时间延长,多不饱和脂肪酸(PUFA)显著降解,饱和脂肪酸(SFA)和反式脂肪酸增加。研究结果凸显了不同植物油之间热稳定性程度的差异,与传统向日葵油相比,高油酸向日葵油和混合油对热降解表现出更强的抗性。本研究强调了选择具有良好脂肪酸组成的油用于高温烹饪的重要性,以尽量减少与食用降解油相关的不良健康影响。此外,该研究为优化油的混合以提高热稳定性和保持营养质量提供了见解,这对消费者健康和食品工业实践至关重要。