Baig Ayesha, Zubair Muhammad, Sumrra Sajjad Hussain, Nazar Muhammad Faizan, Zafar Muhammad Nadeem, Jabeen Kausar, Hassan Muhammad Bilal, Rashid Umer
Department of Chemistry, University of Gujrat, Gujrat, 50700, Pakistan.
Department of Chemistry, University of Education Lahore, Multan Campus, Lahore, Pakistan.
BMC Chem. 2022 Jan 17;16(1):3. doi: 10.1186/s13065-022-00796-z.
The subcontinent is famous for its variety of seasonal foods cooked in vegetable seed cooking oils at elevated heating. Oils are often of poor quality that effect to consumer health. The work, therefore, planned to examine the effects of heat on the quality of mixed canola cooking oils (MCCOs). MCCOs were analyzed by preparing volatile fatty acid methyl esters (FAMEs) and for physiochemical properties.
A major change was observed in the FAs composition of various MCCOs as coded K-1 to K-5. MCCOs were found rich in unsaturated 9-octadecanoic acid (oleic acid C) and 9, 12-octadecadienoic acid (linoleic acid C) along saturated octadecanoic acid (stearic acid C). Results reveals that canola oil samples are mixed in the range of 4-30% with other vegetable oils and animal fats. The quality of canola cooking oils further reduced after heating to 100 °C, 200 °C and 350 °C, respectively. Quality parameters of MCCOs were significantly altered after heating and found as color (510-520 nm to 570-600 nm), mass 220-237 g to 210-225 g, volume 250 mL to 239 mL, pH (6.76-6.89), specific gravity (0.87-0.92), refractive index (1.471-1.475), saponification value (SV) (0.7-2.5), un-saponifiable matter (2.4-9.8%) and acid value (AV) (1.20-5.0 mg KOH).
Heating of oils at elevated temperature have shown a significant effect on pH, specific gravity and un-saponifiable matter (p-value < 0.05). Large changes in the physicochemical parameters and FAs composition help to develop a conclusion that cooking at high temperatures affects the quality of mixed canola cooking oils.
该次大陆以其在高温下用植物籽油烹制的各种季节性食物而闻名。这些油的质量往往较差,会影响消费者健康。因此,这项研究计划检测加热对混合油菜籽油(MCCOs)质量的影响。通过制备挥发性脂肪酸甲酯(FAMEs)并分析其理化性质对MCCOs进行了检测。
观察到不同编码为K-1至K-5的MCCOs的脂肪酸组成发生了重大变化。发现MCCOs富含不饱和9-十八碳烯酸(油酸C)和9,12-十八碳二烯酸(亚油酸C)以及饱和十八烷酸(硬脂酸C)。结果表明,油菜籽油样品与其他植物油和动物脂肪的混合比例在4%-30%之间。分别加热至100℃、200℃和350℃后,油菜籽烹饪油的质量进一步下降。加热后,MCCOs的质量参数发生了显著变化,分别为颜色(从510-520nm变为570-600nm)、质量(从220-237g变为210-225g)、体积(从250mL变为239mL)、pH值(6.76-6.89)、比重(0.87-0.92)、折射率(1.471-1.475)、皂化值(SV)(0.7-2.5)、不皂化物(2.4-9.8%)和酸值(AV)(1.20-5.0mg KOH)。
高温加热油对pH值、比重和不皂化物有显著影响(p值<0.05)。理化参数和脂肪酸组成的巨大变化有助于得出这样的结论:高温烹饪会影响混合油菜籽烹饪油的质量。