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城市固体废弃物焚烧灰在地质聚合物混凝土中的应用:抗压强度与浸出特性研究

Utilization of Municipal Solid Waste Incineration (MSWIFA) in Geopolymer Concrete: A Study on Compressive Strength and Leaching Characteristics.

作者信息

Xu Qiyong, Shang Ning, Ko Jae Hac

机构信息

Shenzhen Engineering Laboratory for Eco-Efficient Recycled Materials, School of Environment and Energy, Peking University Shenzhen Graduate School, University Town, Xili, Nanshan District, Shenzhen 518055, China.

Department of Environmental Engineering, Jeju National University, 102 Jejudaehak-ro, Jeju-si 63243, Jeju, Republic of Korea.

出版信息

Materials (Basel). 2024 Sep 20;17(18):4609. doi: 10.3390/ma17184609.

Abstract

This study explores the utilization of municipal solid waste incineration fly ash (MSWIFA) in geopolymer concrete, focusing on compressive strength and heavy metal leachability. MSWIFA was sourced from a Shenzhen waste incineration plant and pretreated by washing to remove soluble salts. Geopolymer concrete was prepared incorporate with washed or unwashed MSWIFA and tested under different pH conditions (2.88, 4.20, and 10.0). Optimal compressive strength was achieved with a Si/Al ratio of 1.5, water/Na ratio of 10, and sand-binder ratio of 0.6. The washing pretreatment significantly enhanced compressive strength, particularly under alkaline conditions, with GP-WFA (washed MSWIFA) exhibiting a 49.6% increase in compressive strength, compared to a 21.3% increase in GP-FA (unwashed MSWIFA). Additionally, GP-WFA's compressive strength reached 41.7 MPa, comparable to that of the control (GP-control) at 43.7 MPa. Leaching tests showed that acidic conditions (pH 2.88) promoted heavy metal leaching, which increased over the leaching time, while an alkaline environment significantly reduced the leachability of heavy metals. These findings highlight the potential of using washed MSWIFA in geopolymer concrete, promoting sustainable construction practices, particularly in alkaline conditions.

摘要

本研究探讨了城市固体废弃物焚烧飞灰(MSWIFA)在地质聚合物混凝土中的应用,重点关注抗压强度和重金属浸出性。MSWIFA取自深圳一家垃圾焚烧厂,并通过水洗进行预处理以去除可溶性盐。制备了掺入水洗或未水洗MSWIFA的地质聚合物混凝土,并在不同pH条件(2.88、4.20和10.0)下进行测试。当硅铝比为1.5、水钠比为10且砂胶比为0.6时,抗压强度达到最佳。水洗预处理显著提高了抗压强度,尤其是在碱性条件下,与掺入未水洗MSWIFA的GP-FA相比,掺入水洗MSWIFA的GP-WFA抗压强度提高了49.6%,而GP-FA提高了21.3%。此外,GP-WFA的抗压强度达到41.7MPa,与抗压强度为43.7MPa的对照样(GP-control)相当。浸出试验表明,酸性条件(pH 2.88)会促进重金属浸出,且随着浸出时间的延长浸出量增加,而碱性环境会显著降低重金属的浸出性。这些发现凸显了在地质聚合物混凝土中使用水洗MSWIFA的潜力,有助于推动可持续建筑实践,尤其是在碱性条件下。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5e31/11433083/71bf5a0cca4b/materials-17-04609-g001.jpg

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