• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

双二苯基氧化膦作为环氧树脂阻燃剂的简便合成

Facile Synthesis of Bis-Diphenylphosphine Oxide as a Flame Retardant for Epoxy Resins.

作者信息

Li Yan, Tian Chong, Cheng Guiqing, Li Chunhui, Wang Zhongwei

机构信息

School of Biological and Chemical Engineering, Qingdao Technical College, Qingdao 266555, China.

College of Materials Science and Engineering, Shandong University of Science and Technology, Qingdao 266590, China.

出版信息

Polymers (Basel). 2024 Sep 18;16(18):2635. doi: 10.3390/polym16182635.

DOI:10.3390/polym16182635
PMID:39339099
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11435574/
Abstract

A phosphorus-containing compound, (oxybis(4,1-phenylene))bis(phenylphosphine oxide) (ODDPO), was successfully synthesized and used as a flame retardant for epoxy resin (EP). The results demonstrated that EP/ODDPO, containing 1.2 wt% phosphorus, achieved a vertical burning V-0 rating, with a limited oxygen index value of 29.2%, indicating excellent flame retardancy. Comprehensive evaluations revealed that ODDPO exhibited both gas-phase and condensed-phase flame-retardant effects on EP, with a particularly notable barrier effect. In addition, the incorporation of ODDPO had a minimal negative impact on the glass transition temperature () and thermal stability of the EP matrix. Compared to unmodified EP (EP-0), the value and initial decomposition temperature of EP/ODDPO-1.2 decreased by only 7.6 °C and 10.0 °C, respectively. Moreover, the introduction of ODDPO significantly improved the hydrophobicity and water absorption resistance of epoxy materials, which is attributed to ODDPO's rigidity and symmetric structure, reducing water molecule permeation. Furthermore, the dielectric properties of ODDPO-modified EP samples were strengthened compared to EP-0, due to the ODDPO's symmetric structure reducing the polarity of the matrix. The above results indicated that ODDPO serves as an excellent flame retardant while enhancing other properties of the EP matrix, thereby contributing to the preparation and application of high-performance epoxy materials.

摘要

一种含磷化合物，双（4,1-亚苯基）双（苯基氧化膦）（ODDPO），被成功合成并用作环氧树脂（EP）的阻燃剂。结果表明，含1.2 wt%磷的EP/ODDPO达到垂直燃烧V-0等级，极限氧指数值为29.2%，表明具有优异的阻燃性。综合评估表明，ODDPO对EP同时表现出气相机理和凝聚相机理的阻燃作用，阻隔效应尤为显著。此外，ODDPO的加入对EP基体的玻璃化转变温度（）和热稳定性的负面影响最小。与未改性的EP（EP-0）相比，EP/ODDPO-1.2的玻璃化转变温度值和初始分解温度分别仅降低了7.6℃和10.0℃。此外，ODDPO的引入显著提高了环氧材料的疏水性和耐吸水性，这归因于ODDPO的刚性和对称结构，减少了水分子的渗透。此外，由于ODDPO的对称结构降低了基体的极性，ODDPO改性的EP样品的介电性能比EP-0有所增强。上述结果表明，ODDPO在提高EP基体其他性能的同时，是一种优异的阻燃剂，从而有助于高性能环氧材料的制备和应用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/ee09b0d8f95b/polymers-16-02635-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/00a985bc7673/polymers-16-02635-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/bc67850301f5/polymers-16-02635-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/c3f160bf92d5/polymers-16-02635-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/76ab20c3b070/polymers-16-02635-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/94794d283c9c/polymers-16-02635-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/a04b595f2ab1/polymers-16-02635-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/545dcc57a7aa/polymers-16-02635-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/ef0032bfb170/polymers-16-02635-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/ee09b0d8f95b/polymers-16-02635-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/00a985bc7673/polymers-16-02635-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/bc67850301f5/polymers-16-02635-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/c3f160bf92d5/polymers-16-02635-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/76ab20c3b070/polymers-16-02635-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/94794d283c9c/polymers-16-02635-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/a04b595f2ab1/polymers-16-02635-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/545dcc57a7aa/polymers-16-02635-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/ef0032bfb170/polymers-16-02635-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5a58/11435574/ee09b0d8f95b/polymers-16-02635-g008.jpg

相似文献

1
Facile Synthesis of Bis-Diphenylphosphine Oxide as a Flame Retardant for Epoxy Resins.双二苯基氧化膦作为环氧树脂阻燃剂的简便合成
Polymers (Basel). 2024 Sep 18;16(18):2635. doi: 10.3390/polym16182635.
2
Synthesis of a Novel Phosphorus-Containing Flame Retardant Curing Agent and Its Application in Epoxy Resins.一种新型含磷阻燃固化剂的合成及其在环氧树脂中的应用。
J Nanosci Nanotechnol. 2016 Mar;16(3):2811-21. doi: 10.1166/jnn.2016.11637.
3
Synthesis of a Novel Flame Retardant Containing Phosphorus, Nitrogen, and Silicon and Its Application in Epoxy Resin.一种含磷、氮、硅新型阻燃剂的合成及其在环氧树脂中的应用
ACS Omega. 2021 Mar 1;6(10):7094-7105. doi: 10.1021/acsomega.1c00076. eCollection 2021 Mar 16.
4
A bio-based phosphaphenanthrene-containing derivative modified epoxy thermosets with good flame retardancy, high mechanical properties and transparency.一种具有良好阻燃性、高机械性能和透明度的生物基含菲磷衍生物改性环氧热固性材料。
RSC Adv. 2021 Sep 17;11(49):30943-30954. doi: 10.1039/d1ra05709j. eCollection 2021 Sep 14.
5
Preparation of High-Transparency Phosphenanthrene-Based Flame Retardants and Studies of Their Flame-Retardant Properties.高透明度菲基阻燃剂的制备及其阻燃性能研究
Polymers (Basel). 2023 Dec 11;15(24):4665. doi: 10.3390/polym15244665.
6
Investigation of the Structure-Property Effect of Phosphorus-Containing Polysulfone on Decomposition and Flame Retardant Epoxy Resin Composites.含磷聚砜对环氧树脂复合材料分解及阻燃性能的结构-性能效应研究
Polymers (Basel). 2019 Feb 21;11(2):380. doi: 10.3390/polym11020380.
7
Synthesis of a Novel P/N-Triazine-Containing Ring Flame Retardant and Its Application in Epoxy Resin.一种新型含P/N-三嗪环阻燃剂的合成及其在环氧树脂中的应用。
Polymers (Basel). 2024 Mar 22;16(7):871. doi: 10.3390/polym16070871.
8
Synthesis and characterization of PEDSCD and its application as a flame retardant in epoxy resins.PEDSCD的合成、表征及其作为环氧树脂阻燃剂的应用。
RSC Adv. 2021 Oct 27;11(55):34849-34859. doi: 10.1039/d1ra06116j. eCollection 2021 Oct 25.
9
Facile Preparation of a Novel Vanillin-Containing DOPO Derivate as a Flame Retardant for Epoxy Resins.一种新型含香草醛的DOPO衍生物作为环氧树脂阻燃剂的简便制备方法。
Materials (Basel). 2022 Apr 27;15(9):3155. doi: 10.3390/ma15093155.
10
Effect of diammonium hydrogen phosphate coated with silica on flame retardancy of epoxy resin.二氧化硅包覆磷酸氢二铵对环氧树脂阻燃性能的影响。
RSC Adv. 2024 Sep 12;14(39):28965-28975. doi: 10.1039/d4ra05513f. eCollection 2024 Sep 4.

引用本文的文献

1
Effects of Organophosphorus Flame Retardants on the Dissipation Factor of Flame-Retardant Polymers.有机磷阻燃剂对阻燃聚合物损耗因子的影响。
Polymers (Basel). 2025 May 5;17(9):1254. doi: 10.3390/polym17091254.

本文引用的文献

1
Silicon Hybridization for the Preparation of Room-Temperature Curing and High-Temperature-Resistant Epoxy Resin.用于制备室温固化和耐高温环氧树脂的硅杂化
Polymers (Basel). 2024 Feb 27;16(5):634. doi: 10.3390/polym16050634.
2
Fabrication of Multifunctional Silylated GO/FeSiAl Epoxy Composites: A Heat Conducting Microwave Absorber for 5G Base Station Packaging.多功能硅烷化氧化石墨烯/铁硅铝环氧树脂复合材料的制备：一种用于5G基站封装的导热微波吸收体
Materials (Basel). 2023 Dec 5;16(24):7511. doi: 10.3390/ma16247511.
3
Comparison of the Properties of Epoxy Resins Containing Various Trifluoromethyl Groups with Low Dielectric Constant.
含不同三氟甲基的低介电常数环氧树脂性能比较
Polymers (Basel). 2023 Jun 28;15(13):2853. doi: 10.3390/polym15132853.
4
Flame-Retardant Cycloaliphatic Epoxy Systems with High Dielectric Performance for Electronic Packaging Materials.用于电子包装材料的具有高介电性能的阻燃脂环族环氧树脂体系。
Int J Mol Sci. 2023 Jan 24;24(3):2301. doi: 10.3390/ijms24032301.
5
Preparation and Characterization of Cardanol-Based Flame Retardant for Enhancing the Flame Retardancy of Epoxy Adhesives.用于提高环氧胶粘剂阻燃性的腰果酚基阻燃剂的制备与表征
Polymers (Basel). 2022 Nov 29;14(23):5205. doi: 10.3390/polym14235205.
6
Significantly Enhanced Electromagnetic Interference Shielding Performances of Epoxy Nanocomposites with Long-Range Aligned Lamellar Structures.具有长程排列层状结构的环氧纳米复合材料的电磁干扰屏蔽性能显著增强
Nanomicro Lett. 2022 Nov 15;14(1):224. doi: 10.1007/s40820-022-00949-8.
7
A Phosphorous-Based Bi-Functional Flame Retardant Based on Phosphaphenanthrene and Aluminum Hypophosphite for an Epoxy Thermoset.基于磷杂菲和次膦酸铝的磷基双官能团阻燃剂用于环氧热固性塑料。
Int J Mol Sci. 2022 Sep 24;23(19):11256. doi: 10.3390/ijms231911256.
8
Development of Low-Shrink Epoxy Putty to Solve Appearance-Quality Defects of Carbon-Fiber-Reinforced Plastic Automotive Exterior Parts.开发低收缩环氧腻子以解决碳纤维增强塑料汽车外部部件的外观质量缺陷。
Materials (Basel). 2021 Oct 26;14(21):6419. doi: 10.3390/ma14216419.
9
A One-Component, Fast-Cure, and Economical Epoxy Resin System Suitable for Liquid Molding of Automotive Composite Parts.一种适用于汽车复合材料部件液体成型的单组分、快速固化且经济的环氧树脂体系。
Materials (Basel). 2018 Apr 27;11(5):685. doi: 10.3390/ma11050685.
10
Intrinsic Flame-Retardant and Thermally Stable Epoxy Endowed by a Highly Efficient, Multifunctional Curing Agent.由高效多功能固化剂赋予的本征阻燃且热稳定的环氧树脂
Materials (Basel). 2016 Dec 12;9(12):1008. doi: 10.3390/ma9121008.