Characterization and ecological risks of microplastics in urban road runoff.

Microplastics (MPs) deposited on urban roads are often flushed into water bodies via drainage systems without treatment, and MP concentrations in the initial road runoff may be particularly high. Yet, there is only a limited understanding of the characteristics, dynamics, and impacts of MPs in urban road runoff. In this study, stormwater and rainwater samples were collected from seven different locations in Hong Kong across 11 rainfall events between February 2021 and September 2022. Characteristics of MPs in the collected samples were analyzed in detail, along with the dynamics of MP concentration in rainfall events, possible influencing factors, and ecological risks. The results show that MP concentration in the initial road runoff is particularly high during a rainfall episode. Overall, the median MP abundance in the collected runoff samples (185 particles/L) was 4.6 times higher than that in rainwater (40 particles/L). The most common polymers identified were polyethylene, polypropylene, and polystyrene, with fragments being the dominant shape. Over 60 % of MP sizes were smaller than 300 μm in the runoff samples. Additionally, risk assessments based on the Polymer Risk Index (PRI) classified most road sites in pollution classes II to III (PRI = 13.3-138.0), indicating moderate to high ecological risks. It appears that MP abundance in the initial runoff was significantly influenced by seasonal changes. These findings highlight urban roads as a major source of MP pollution in stormwater runoff and emphasize the importance of addressing the initial runoff in pollution control.