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含磷阻燃化学品对使用脲醛树脂生产的刨花板影响的研究。

Investigation of the Effects of Phosphate-Containing Flame-Retardant Chemicals on Particleboards Produced Using Urea-Formaldehyde Resin.

作者信息

Uygur Nazan, Doganci Erdinc, Aytac Ayse

机构信息

Department of Polymer Science and Technology, Kocaeli University, 41001 Kocaeli, Turkey.

Department of Chemistry and Chemical Processing Technology, Kocaeli University, 41140 Kocaeli, Turkey.

出版信息

ACS Omega. 2024 Sep 14;9(38):39513-39522. doi: 10.1021/acsomega.4c03419. eCollection 2024 Sep 24.

Abstract

In this study, urea-formaldehyde resins containing different phosphate-based flame retardants (FRs) were prepared to produce wood-based panels (medium-density fiberboard, particleboard, and veneer board), and their flammability properties were investigated. The changes in the gelation times were investigated when the phosphate-containing FRs used in different amounts were mixed with the resin. Chemicals that have both hardener and flame-retardant properties at the same time have been studied. In addition, the pH and thermal analyses of the resin and flame-retardant mixtures prepared in this study were performed by a pH meter and thermogravimetric analysis, respectively. The limiting oxygen index, UL-94 vertical burning, and cone calorimetry tests on the samples with the best combustion characteristics were carried out by sizing the particleboards in accordance with the standards and applying the prepared flame-retardant resins on them. The distribution of flame-retardant resin on the particleboard surface was investigated for the samples prepared by scanning electron microscopy. As a result of the analyses, it was determined that the samples containing 20% ammonium polyphosphate had good nonflammability properties.

摘要

在本研究中,制备了含有不同磷酸盐基阻燃剂(FRs)的脲醛树脂,以生产人造板(中密度纤维板、刨花板和胶合板),并研究了它们的燃烧性能。研究了不同用量的含磷FRs与树脂混合时凝胶化时间的变化。同时研究了兼具固化剂和阻燃性能的化学品。此外,本研究中制备的树脂和阻燃剂混合物的pH值和热分析分别通过pH计和热重分析进行。通过按照标准对刨花板进行尺寸测量并在其上施加制备好的阻燃树脂,对具有最佳燃烧特性的样品进行极限氧指数、UL-94垂直燃烧和锥形量热法测试。通过扫描电子显微镜对制备的样品研究了阻燃树脂在刨花板表面的分布。分析结果表明,含有20%聚磷酸铵的样品具有良好的不燃性能。

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