Gu Haoyu, Dong Xiaoyu, Zhang Qiankun, Chi Dequan, Zhang Yang, Cheng Zhongjun, Lv Tong, Xie Zhimin, Xu Yongjun, Zhang Dongjie, Liu Yuyan
School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150001, P. R. China.
Research Institute of Aerospace Special Materials and Processing Technology, Beijing 100174, P. R. China.
ACS Appl Mater Interfaces. 2024 Oct 9;16(40):54627-54635. doi: 10.1021/acsami.4c11911. Epub 2024 Sep 30.
The development of intelligent reversible reconfigurable metamaterials has great significance in constructing three-dimensional metamaterials and introducing reversible tunability into metamaterials. Here, we introduce an intelligent metamaterial consisting of a two-way shape memory polymer (2W-SMP) ethylene vinyl acetate copolymer (EVA) actuator substrate and a patterned flexible-rigid film. Mechanical buckling of the 2W-SMP substrate was controlled by thermal stimulation. This makes it possible to afford an ability to initiate 3D structure formation or shape reconfiguration remotely in an on-demand fashion. In addition, the shape of the 2W-SMP substrate is temperature-dependent, allowing repeatable reversible deformation through temperature control after a single programming. Therefore, the electromagnetic properties of metamaterials can also be repeatedly and reversibly tuned between 9.15 and 10.82 GHz. Experimental demonstrations include the deformation and tunable electromagnetic properties of intelligent reversible reconfigurable metamaterial cells. The results create many opportunities for advanced programmable three-dimensional metamaterials.
智能可逆可重构超材料的发展对于构建三维超材料以及将可逆可调性引入超材料具有重要意义。在此,我们介绍一种智能超材料,它由双向形状记忆聚合物(2W-SMP)乙烯-醋酸乙烯酯共聚物(EVA)致动器基板和图案化的柔性-刚性薄膜组成。2W-SMP基板的机械屈曲通过热刺激来控制。这使得能够以按需方式远程启动3D结构形成或形状重构。此外,2W-SMP基板的形状取决于温度,在单次编程后通过温度控制可实现可重复的可逆变形。因此,超材料的电磁特性也可在9.15至10.82 GHz之间反复且可逆地调谐。实验演示包括智能可逆可重构超材料单元的变形和可调电磁特性。这些结果为先进的可编程三维超材料创造了许多机会。