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双硝基环氧化合物的合成及其在双（噻唑烷-2-硫酮）、双（二硫代氨基甲酸盐）、双（黄原酸盐）和双（噻唑）合成中的应用。

Synthesis of bisnitroepoxides and their applications in the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles).

作者信息

Halimehjani Azim Ziyaei, Mohammadlou Mahsa, Badali Elham, Habibi Azizollah

机构信息

Department of Chemistry, Sharif University of Technology, Tehran, 11155-9516, Iran.

Faculty of Chemistry, Kharazmi University, 49 Mofateh Street, P. O. Box 15719-14911, Tehran, Iran.

出版信息

Sci Rep. 2024 Sep 30;14(1):22592. doi: 10.1038/s41598-024-74156-3.

DOI:10.1038/s41598-024-74156-3
PMID:39349543
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11442458/
Abstract

Novel bis(nitroepoxides) were prepared based on terephthaldehyde and isophthaladehyde and their reactions with diversities of nucleophiles such as primary and secondary amine-based dithiocarbamic acids, xanthates, and ammonia-based dithiocarbmamates were investigated for the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles), respectively. It provides simple access to complex molecules in one step in high to excellent yields.

摘要

基于对苯二甲醛和间苯二甲醛制备了新型双（硝基环氧化合物），并研究了它们与多种亲核试剂（如伯胺和仲胺基二硫代氨基甲酸、黄原酸盐和氨代二硫代氨基甲酸盐）的反应，分别用于合成双（噻唑烷-2-硫酮）、双（二硫代氨基甲酸盐）、双（黄原酸盐）和双（噻唑）。它提供了一种简单的方法，能够一步以高至优异的产率合成复杂分子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/d219906aaae0/41598_2024_74156_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/ea6f3ba6e250/41598_2024_74156_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/b3460a3d55ca/41598_2024_74156_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/f67cb1ab8aea/41598_2024_74156_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/395f22741cbb/41598_2024_74156_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/a295f4cb4978/41598_2024_74156_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/d219906aaae0/41598_2024_74156_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/ea6f3ba6e250/41598_2024_74156_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/b3460a3d55ca/41598_2024_74156_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/f67cb1ab8aea/41598_2024_74156_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/395f22741cbb/41598_2024_74156_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/a295f4cb4978/41598_2024_74156_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/d219906aaae0/41598_2024_74156_Fig6_HTML.jpg

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本文引用的文献

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