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双硝基环氧化合物的合成及其在双(噻唑烷-2-硫酮)、双(二硫代氨基甲酸盐)、双(黄原酸盐)和双(噻唑)合成中的应用。

Synthesis of bisnitroepoxides and their applications in the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles).

作者信息

Halimehjani Azim Ziyaei, Mohammadlou Mahsa, Badali Elham, Habibi Azizollah

机构信息

Department of Chemistry, Sharif University of Technology, Tehran, 11155-9516, Iran.

Faculty of Chemistry, Kharazmi University, 49 Mofateh Street, P. O. Box 15719-14911, Tehran, Iran.

出版信息

Sci Rep. 2024 Sep 30;14(1):22592. doi: 10.1038/s41598-024-74156-3.

Abstract

Novel bis(nitroepoxides) were prepared based on terephthaldehyde and isophthaladehyde and their reactions with diversities of nucleophiles such as primary and secondary amine-based dithiocarbamic acids, xanthates, and ammonia-based dithiocarbmamates were investigated for the synthesis of bis(thiazolidine-2-thiones), bis(dithiocarbamates), bis(xanthates) and bis(thiazoles), respectively. It provides simple access to complex molecules in one step in high to excellent yields.

摘要

基于对苯二甲醛和间苯二甲醛制备了新型双(硝基环氧化合物),并研究了它们与多种亲核试剂(如伯胺和仲胺基二硫代氨基甲酸、黄原酸盐和氨代二硫代氨基甲酸盐)的反应,分别用于合成双(噻唑烷-2-硫酮)、双(二硫代氨基甲酸盐)、双(黄原酸盐)和双(噻唑)。它提供了一种简单的方法,能够一步以高至优异的产率合成复杂分子。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/346d/11442458/ea6f3ba6e250/41598_2024_74156_Fig1_HTML.jpg

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