锑烯六边形的氟化
Fluorination of antimonene hexagons.
作者信息
Fickert Michael, Martinez-Haya Rebeca, López-Alcalá Diego, Hauke Frank, Baldoví José J, Hirsch Andreas, Abellán Gonzalo
机构信息
Department of Chemistry and Pharmacy and Joint Institute of Advanced Materials and Processes (ZMP) Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU) Fürth, 90762, Germany.
Instituto de Ciencia Molecular (ICMol) Universidad de Valencia, Valencia 46980, Spain. gonzalo.abellan.uv.es.
出版信息
Chem Commun (Camb). 2024 Nov 12;60(91):13336-13339. doi: 10.1039/d4cc03423f.
Fluorination of two-dimensional (2D) antimonene hexagons synthesized through a colloidal bottom-up approach has been explored using microwave-induced plasma and reactive ion etching fluorination strategies through the generation of CF. The stability of the fluorine bond has been corroborated through DFT calculations. This work paves the way for further halogen-derivative modifications of heavy 2D pnictogens.
通过胶体自下而上方法合成的二维锑烯六边形的氟化已经通过微波诱导等离子体和通过产生CF的反应离子蚀刻氟化策略进行了探索。氟键的稳定性已通过密度泛函理论（DFT）计算得到证实。这项工作为进一步对重二维氮族元素进行卤素衍生物修饰铺平了道路。
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