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基于聚(3,4-乙撑二氧噻吩):聚苯乙烯磺酸盐的可穿戴柔性温度传感器及用于人体监测的集成传感矩阵

PEDOT:PSS-Based Wearable Flexible Temperature Sensor and Integrated Sensing Matrix for Human Body Monitoring.

作者信息

Zhu Zhengfang, Su Yi, Chen Jing, Zhang Jinyong, Liang Lixin, Nie Zedong, Tang Wei, Liang Yongsheng, Li Hui

机构信息

College of Big Data and Internet, Shenzhen Technology University, Shenzhen 518118, Guangdong, China.

Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen 518055, Guangdong, China.

出版信息

ACS Appl Mater Interfaces. 2024 Oct 3. doi: 10.1021/acsami.4c11251.

Abstract

Flexible temperature sensors have been widely used in electronic skins and health monitoring. Body temperature as one of the key physiological signals is crucial for detecting human body's abnormalities, which necessitates high sensitivity, quick responsiveness, and stable monitoring. In this paper, we reported a resistive temperature sensor designed as an ultrathin laminated structure with a serpentine pattern and a bioinspired adhesive layer, which was fabricated with a composite of poly(3,4-ethylenedioxythiophene)-poly(styrenesulfonate)/single-wall carbon nanotubes/reduced graphene oxide (PEDOT:PSS/SWCNTs/rGO) and polydimethylsiloxane (PDMS). The temperature sensor exhibited a high temperature sensitivity of 0.63% °C, coupled with outstanding linearity of 0.98 within 25-45 °C. Furthermore, it showed fast response and recovery speeds of 4.8 and 5.8 s, respectively, between 25 and 36 °C. It also demonstrated exceptional stability when subjected to stress and bending disturbances with the maximum bending interference deviation of 0.03%. Additionally, it displayed good cyclic stability over a broad temperature range from 25 to 85 °C, and the standard deviation at 25 °C is 0.14%. A series of experiments including blowing detection, respiratory monitoring with or without a mask, and during rest or sleep were conducted to show the potential of the flexible temperature sensors in human body monitoring. Furthermore, a 4 × 4 flexible temperature sensor matrix was integrated to detect and map objects such as wrenches and blood vessels through human hand skin. The results were consistent with those of infrared measurements. The flexible temperature sensor is capable of real-time temperature monitoring and has the potential in tracking human respiration, assessing sleep quality, and mapping the temperature of various objects.

摘要

柔性温度传感器已广泛应用于电子皮肤和健康监测领域。体温作为关键的生理信号之一,对于检测人体异常情况至关重要,这就要求温度传感器具有高灵敏度、快速响应能力和稳定的监测性能。在本文中,我们报道了一种电阻式温度传感器,其设计为具有蛇形图案的超薄层压结构以及仿生粘合剂层,该传感器由聚(3,4 - 乙撑二氧噻吩) - 聚(苯乙烯磺酸盐)/单壁碳纳米管/还原氧化石墨烯(PEDOT:PSS/SWCNTs/rGO)与聚二甲基硅氧烷(PDMS)的复合材料制成。该温度传感器表现出0.63% /°C的高温度灵敏度,在25 - 45°C范围内具有0.98的出色线性度。此外,在25至36°C之间,其响应速度和恢复速度分别为4.8秒和5.8秒。在受到应力和弯曲干扰时,它还表现出卓越的稳定性,最大弯曲干扰偏差为0.03%。另外,在25至85°C的宽温度范围内,它显示出良好的循环稳定性,在25°C时的标准偏差为0.14%。进行了一系列实验,包括吹气检测、有无口罩时的呼吸监测以及休息或睡眠期间的监测,以展示柔性温度传感器在人体监测中的潜力。此外,集成了一个4×4的柔性温度传感器矩阵,通过人手皮肤检测并绘制诸如扳手和血管等物体的温度分布图。结果与红外测量结果一致。该柔性温度传感器能够进行实时温度监测,并且在跟踪人体呼吸、评估睡眠质量以及绘制各种物体的温度分布图方面具有潜力。

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