Department of Chemistry, Government College University Faisalabad, Faisalabad, Pakistan.
Department of Chemistry "Giacomo Ciamician" University of Bologna, Bologna, Italy.
PLoS One. 2024 Oct 4;19(10):e0308117. doi: 10.1371/journal.pone.0308117. eCollection 2024.
The primary objective of this research was to investigate nutritional composition of soybean, canola, cottonseed, palm and rapeseed oils under and the effect of storage conditions on their oxidative stability. Nutritional quality of selected seed oils was determined in term of fatty acids, tocopherols and tocotrienols compositions, total phenolic, total flavonoids and mineral contents. High resolution gas chromatography (HR-GC) analysis showed the presence of saturated, monounsaturated and polyunsaturated fatty acids having range from 9.21-43.25, 27.01-58.87 and 29.23-57.75 g/100g, respectively in all the oils. High performance liquid chromatography (HPLC) analysis revealed that γ-tocopherol was the major tocopherol followed by α-tocopherol in most of the oils. Spectrophotometric analysis showed that the total phenolic contents were 2.84-14.44 mg/g of oil, measured as gallic acid equivalent and total flavonoid contents were 0.44-1.56 mg/g of oil, measure as quercetin equivalent. Inductively coupled plasma-optical emission spectrophotometer analysis revealed that Mg, Fe and Mn were present in higher concentration ranging from 57.14-114.85, 126.87-460.06 and 106.85-538.39 μg/ml respectively. For study the effect of various storage conditions on the oxidation parameters, free fatty acid, peroxide value, para-anisidine value, conjugated dienes and trienes values were determined and ranging from 0.48-1.65, 10.65-40.15 meq/kg, 9.98-33.30, 8.74-28.41 and 3.86-15.02, respectively after 90 days storage. Statistical analysis revealed that various storage conditions exerted significant (p ≤ 0.05) effect on the oxidative stability of selected oils to different extent.
本研究的主要目的是研究大豆、油菜籽、棉籽油、棕榈油和油菜籽油的营养成分,并研究储存条件对其氧化稳定性的影响。选择的种子油的营养质量是根据脂肪酸、生育酚和三烯生育酚的组成、总酚、总类黄酮和矿物质含量来确定的。高分辨率气相色谱(HR-GC)分析表明,所有油中都存在饱和、单不饱和和多不饱和脂肪酸,其范围分别为 9.21-43.25、27.01-58.87 和 29.23-57.75g/100g。高效液相色谱(HPLC)分析表明,γ-生育酚是大多数油中主要的生育酚,其次是α-生育酚。分光光度分析表明,总酚含量为 2.84-14.44mg/g 油,以没食子酸当量计;总黄酮含量为 0.44-1.56mg/g 油,以槲皮素当量计。电感耦合等离子体-光学发射光谱仪分析表明,Mg、Fe 和 Mn 的浓度较高,范围分别为 57.14-114.85μg/ml、126.87-460.06μg/ml 和 106.85-538.39μg/ml。为了研究不同储存条件对氧化参数的影响,测定了游离脂肪酸、过氧化物值、对茴香胺值、共轭二烯和三烯值,分别为 0.48-1.65、10.65-40.15meq/kg、9.98-33.30、8.74-28.41 和 3.86-15.02,储存 90 天后。统计分析表明,不同的储存条件对所选油的氧化稳定性有不同程度的显著(p≤0.05)影响。