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聚合物/表面活性剂复合调控体系各组分在砂砾岩油藏注采通道中的吸附行为

Adsorption Behavior of Different Components of a Polymer/Surfactant Composite Control System along an Injection-Production Channel in Sand Conglomerate Reservoirs.

作者信息

Wang Yuanyuan, Qin Dapeng, Jiang Shengdong

机构信息

Key Laboratory of Enhanced Oil & Gas Recovery of Ministry of Education, Northeast Petroleum University, Daqing 163318, P. R. China.

No.6 Oil Production Plant, PetroChina Changqing Oilfield Company, Xi'an 710018, China.

出版信息

ACS Omega. 2024 Sep 23;9(39):40665-40675. doi: 10.1021/acsomega.4c04906. eCollection 2024 Oct 1.

DOI:10.1021/acsomega.4c04906
PMID:39371979
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11447724/
Abstract

Sandy conglomerate reservoirs have become an important replacement area for unconventional energy to increase reserves and production. The polymer/surfactant composite control flooding system can effectively alleviate the water flooding front breakthrough caused by the interlayer or plane heterogeneity of the sand conglomerate reservoir and is an effective production method to reduce the water cutoff of the well and increase the oil recovery. In the process of controlling the oil displacement process of the system, the chromatographic separation effect was found due to the different viscosities of each component and the adsorption difference between the components and the rock, which weakened the development effect of the reservoir. It is necessary to study the adsorption law of each component of the complex controlled displacement system along the injection-production channel in the sand conglomerate reservoir. In this study, the microstructure and mineral composition of sandy conglomerates were determined by scanning electron microscopy and X-ray diffraction tests. The main particle size distribution was counted through a rock particle sieving experiment. A new characterization method called the large-size core physical model was used. The composite control system of sulfonate and betaine was used as the surfactant component, and the adsorption degree of each component in the displacement process was analyzed. The experimental results showed that the mass fraction of the sandy conglomerate increased with the decrease in particle size. The particles with a size of less than 0.08 mm account for a relatively high proportion, with a mass fraction of 60%. The content of brittle minerals, such as quartz and feldspar, in the glutenite was relatively high, and micrometer-sized pores and fractures were developed. The main factors affecting the viscosity of the composite system were the concentration and molecular weight of the polymer. The increase of injection volume of the flooding system is conducive to the maintenance of ultralow interfacial tension migration to the deep core. In the displacement process, when the polymer molecular chain was cut to a certain extent, the effect of throat shear was also slowed due to the short molecular chain. However, the shortened polymer molecules were more easily adsorbed on the surface of rock particles and the adsorption rate increased. The adsorption capacity of each component gradually decreased with the increase of the injection volume and injection concentration. The relative content of the composite control system and crude oil affects the type of emulsion, which undergoes a corresponding transformation during the driving process from a water-in-oil emulsion to an oil-in-water one. The research results of this paper enrich the mechanism of enhancing oil recovery of sand conglomerate reservoirs by polymer-surfactant composite regulation technology.

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/f9728880cf79/ao4c04906_0013.jpg
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https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/5545cbb248c0/ao4c04906_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/f347bb12527d/ao4c04906_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/af031980bee2/ao4c04906_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/bf282b203677/ao4c04906_0008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/95f432799ae2/ao4c04906_0009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/2ed1270de1e9/ao4c04906_0010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/bacb0bfb3d49/ao4c04906_0011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/7a38e7d552e4/ao4c04906_0012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7e15/11447724/f9728880cf79/ao4c04906_0013.jpg
摘要

砂砾岩油藏已成为非常规能源增加储量和产量的重要接替领域。聚合物/表面活性剂复合调控驱油体系能有效缓解砂砾岩油藏层间或平面非均质性造成的水驱前缘突破,是降低油井含水率、提高采收率的有效开采方式。在该体系驱油过程控制中,发现各组分黏度不同以及组分与岩石间吸附差异导致了色谱分离效应,削弱了油藏开发效果。有必要研究复合驱替体系各组分在砂砾岩油藏注采通道沿线的吸附规律。本研究通过扫描电子显微镜和X射线衍射试验确定了砂砾岩的微观结构和矿物组成,通过岩屑筛分实验统计了主要粒径分布,采用一种名为大尺寸岩心物理模型的新型表征方法,以磺酸盐和甜菜碱复合体系作为表面活性剂组分,分析了各组分在驱替过程中的吸附程度。实验结果表明,砂砾岩质量分数随粒径减小而增大,粒径小于0.08mm的颗粒占比较高,质量分数为60%。砂砾岩中石英、长石等脆性矿物含量较高,发育微米级孔隙和裂缝。影响复合体系黏度的主要因素是聚合物的浓度和分子量。驱油体系注入量增加有利于超低界面张力向岩心深部运移的维持。在驱替过程中,聚合物分子链被剪切到一定程度时,因分子链变短,喉道剪切作用也减缓,但缩短的聚合物分子更易吸附在岩石颗粒表面,吸附速率增大。各组分的吸附量随注入量和注入浓度的增加而逐渐降低。复合调控体系与原油的相对含量影响乳状液类型,在驱替过程中经历从油包水型乳状液到水包油型乳状液的相应转变。本文研究成果丰富了聚合物-表面活性剂复合调控技术提高砂砾岩油藏采收率的机理。

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本文引用的文献

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Heads or tails? The synthesis, self-assembly, properties and uses of betaine and betaine-like surfactants.头还是尾?甜菜碱和类似甜菜碱表面活性剂的合成、自组装、性质和用途。
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