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纳米结构多样性:异构芘 - 胆甾烷两亲分子自组装成片状、管状和蠕虫状形态。

Nanostructural diversity: self-assembly of isomeric pyrene-cholane amphiphiles into sheets, tubes, and worm-like morphologies.

作者信息

Ehret Edouard, Iacovache Ioan, Langenegger Simon M, Zuber Benoît, Häner Robert

机构信息

Department of Chemistry, Biochemistry, Pharmaceutical Sciences, University of Bern Freiestrasse 3 CH-3012 Bern Switzerland

Institute for Anatomy, University of Bern Baltzerstrasse 2 CH-3012 Bern Switzerland.

出版信息

RSC Adv. 2024 Oct 4;14(43):31498-31501. doi: 10.1039/d4ra06420h. eCollection 2024 Oct 1.

DOI:10.1039/d4ra06420h
PMID:39372046
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11450553/
Abstract

Phosphodiester-linked cholane-pyrene-cholane trimers self-assemble into sheet-, tube- and worm-like nanostructures in aqueous conditions. The nanotubes and worm-like assemblies exist as single- or multi-walled objects.

摘要

磷酸二酯连接的胆甾烷-芘-胆甾烷三聚体在水性条件下自组装成片状、管状和蠕虫状纳米结构。纳米管和蠕虫状聚集体以单壁或多壁形式存在。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/7b6817c04ac2/d4ra06420h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/977ea040f6ae/d4ra06420h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/f6c140a67189/d4ra06420h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/7b6817c04ac2/d4ra06420h-f3.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/977ea040f6ae/d4ra06420h-f1.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/f6c140a67189/d4ra06420h-f2.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/05a0/11450553/7b6817c04ac2/d4ra06420h-f3.jpg

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Saddles as rotational locks within shape-assisted self-assembled nanosheets.鞍状物作为形状辅助自组装纳米片中的旋转锁。
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