三氯代 -（1,10 - 菲咯啉 -κ,'）苯基锡（IV）的晶体结构与 Hirshfeld 表面分析
Crystal structure and Hirshfeld surface analysis of tri-chlorido-(1,10-phenanthroline-κ ,')phenyltin(IV).
作者信息
Benlatreche Tarek, Bensegueni Mohamed Abdellatif, Dénès Georges, Golhen Stéphane, Merazig Hocine
机构信息
Environmental and Structural Molecular Chemistry Research Unit URCHEMS Faculty of Exact Sciences University of Constantine 1-Mentouri Brothers 25000 Algeria.
National Higher School for Hydraulics, Abdellah Arbaoui, Blida, Algeria.
出版信息
Acta Crystallogr E Crystallogr Commun. 2024 Sep 24;80(Pt 10):1039-1043. doi: 10.1107/S2056989024009150. eCollection 2024 Sep 1.
The title compound, [Sn(CH)Cl(CHN)], which was obtained by the reaction between 1,10-phenanthroline and phenyl-tin trichloride in methanol, exhibits intra-molecular hydrogen-bonding inter-actions involving the chlorine and hydrogen atoms. Crystal cohesion is ensured by inter-molecular C-H⋯Cl hydrogen bonds, as well as -⋯π and π-stacking inter-actions involving three different aromatic rings with centroid-centroid distances of 3.6605 (13), 3.9327 (14) and 3.6938 (12) Å]. Hirshfeld surface analysis and the associated two-dimensional fingerprint plots reveal significant contributions from H⋯H (30.7%), Cl⋯H/H⋯Cl (32.4%), and C⋯H/H⋯C (24.0%) contacts to the crystal packing while the C⋯C (6.2%), C⋯Cl/Cl⋯C (4.1%), and N⋯H/H⋯N (1.7%) inter-actions make smaller contributions.
标题化合物[Sn(CH)Cl(CHN)]是通过1,10 - 菲咯啉与苯基三氯化锡在甲醇中反应得到的，它表现出涉及氯原子和氢原子的分子内氢键相互作用。分子间的C - H⋯Cl氢键以及涉及三个不同芳香环的 - ⋯π和π堆积相互作用确保了晶体的凝聚，其质心 - 质心距离分别为3.6605 (13)、3.9327 (14)和3.6938 (12) Å]。 Hirshfeld表面分析和相关的二维指纹图谱显示，H⋯H（30.7%）、Cl⋯H/H⋯Cl（32.4%）和C⋯H/H⋯C（24.0%）接触对晶体堆积有显著贡献，而C⋯C（6.2%）、C⋯Cl/Cl⋯C（4.1%）和N⋯H/H⋯N（1.7%）相互作用的贡献较小。
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