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磁感应加热驱动的氨分解制氢快速冷启动

Magnetic Induction Heating-Driven Rapid Cold Start of Ammonia Decomposition for Hydrogen Production.

作者信息

Zhang Ruiqi, Liu Xingwu, Song Ningning, He Jiahao, Cen Zeyan, Li Chengyu, Wang Maolin, Tang Haoyi, Liu Wei, Ren Xiao, Ma Ding

机构信息

Beijing National Laboratory for Molecular Sciences, New Cornerstone Science Laboratory, College of Chemistry and Molecular Engineering, Peking University, Beijing 100871, China.

College of Mathematics and Physics, Beijing University of Chemical Technology, Beijing 100029, China.

出版信息

J Am Chem Soc. 2024 Oct 23;146(42):28635-28641. doi: 10.1021/jacs.4c10851. Epub 2024 Oct 9.

Abstract

The advantages of ammonia as a hydrogen carrier have led to proposals for on-site hydrogen production through its decomposition. Rapid cold start of ammonia decomposition is crucial for applications such as ammonia-powered vehicles, but conventional heating methods are challenged by the high decomposition temperature of ammonia. In this study, we successfully achieved the rapid cold start of ammonia decomposition using Co nanoparticle catalysts driven by magnetic induction heating, demonstrating excellent catalytic performance and stability. The magnetic induction heating-driven ammonia decomposition system was integrated with a hydrogen fuel cell, proving its ability to achieve the cold start of ammonia decomposition within 10 s, as demonstrated by comparative experiments using 75% H-25% N from a gas cylinder as the control. This study provides a deeper understanding of hysteresis heating catalysis, promoting the practical use of ammonia as a hydrogen carrier for rapid hydrogen production in the energy industry.

摘要

氨作为氢载体的优势促使人们提出通过其分解进行现场制氢的方案。氨分解的快速冷启动对于氨动力车辆等应用至关重要,但传统加热方法面临着氨分解温度高的挑战。在本研究中,我们使用磁感应加热驱动的钴纳米颗粒催化剂成功实现了氨分解的快速冷启动,展现出优异的催化性能和稳定性。磁感应加热驱动的氨分解系统与氢燃料电池集成,通过使用来自气瓶的75%H-25%N作为对照的对比实验证明,其能够在10秒内实现氨分解的冷启动。本研究为滞后加热催化提供了更深入的理解,推动了氨作为氢载体在能源行业中快速制氢的实际应用。

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