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基于LaCaSrMnO巨磁热效应的架空输电线路先进防冰除冰策略

Advanced Anti-icing and Deicing Strategies for Overhead Power Transmission Lines Based on Giant Magnetocaloric Effect of LaCaSrMnO.

作者信息

Lei Qi, Zhang Ji, Lashgari Hamid, Wang Danyang, Zeng Rong, Li Sean

机构信息

School of Materials Science and Engineering, UNSW Materials and Manufacturing Futures Institute, The University of New South Wales, Sydney, NSW 2052, Australia.

China Hubei Carbon Emission Exchange, Wuhan 430100, P.R. China.

出版信息

ACS Appl Mater Interfaces. 2024 Oct 23;16(42):57032-57039. doi: 10.1021/acsami.4c10999. Epub 2024 Oct 11.

Abstract

Perovskite manganates (AMnO) exhibit diverse structural, thermal, electrical, and magnetic properties. Their strong magnetocaloric effect (MCE) near the Curie temperature () makes them ideal for magnetic-thermal anti-icing and deicing in power transmission lines. Below , ferromagnetic AMnO produces heat through multiple mechanisms, with the changing magnetic field induced by the strong AC current, causing heat through magnetic hysteresis and eddy currents, alongside the direct MCE. Above , no heating is generated, as MCE is unfavorable, thus preventing additional energy loss at elevated temperatures. In this work, LaCaSrMnO with close to 0 °C were synthesized by solid-state reaction. It is found that particle size >10 μm is beneficial for a large MCE, based on the results of particle size dependence of MCE. The resulting maximum magnetic entropy change at 277 K is 7.69 J·kg·K, and an adiabatic temperature change of 3.87 K at 277 K is achieved under 5 T. The prototype cable is fabricated using a well-established wire drawing process. A climate-simulation chamber is employed for the anti-icing and deicing experiments. The prototype cables demonstrated a strong capability for deicing and anti-icing. This simple and cost-effective prototype cable shows significant potential for mitigating the icing problem of overhead high-voltage power transmission lines.

摘要

钙钛矿锰酸盐(AMnO)展现出多样的结构、热学、电学和磁学性质。它们在居里温度()附近具有很强的磁热效应(MCE),这使其成为输电线路磁热防冰和除冰的理想材料。在居里温度以下,铁磁体AMnO通过多种机制产生热量,强交流电流感应出变化的磁场,通过磁滞和涡流产生热量,同时还有直接的磁热效应。在居里温度以上,由于磁热效应不利,不会产生热量,从而防止在高温下额外的能量损失。在这项工作中,通过固态反应合成了居里温度接近0°C的LaCaSrMnO。基于磁热效应的粒径依赖性结果发现,粒径>10μm有利于产生大的磁热效应。在277K时产生的最大磁熵变为7.69J·kg·K,在5T磁场下,277K时的绝热温度变化为3.87K。原型电缆是使用成熟的拉丝工艺制造的。采用气候模拟室进行防冰和除冰实验。原型电缆展示出很强的除冰和防冰能力。这种简单且经济高效的原型电缆在缓解架空高压输电线路结冰问题方面显示出巨大潜力。

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