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以秋葵秸秆为原料绿色合成氧化锌及镍掺杂氧化锌用于光催化降解普施安红MX - 5B

Green synthesis of ZnO and Ni-doped ZnO from okra stalks for the photocatalytic degradation of Procion Red MX-5B.

作者信息

Horoz Sabit, Orak Ceren, Biçer Emre

机构信息

Department of Engineering Fundamental Sciences, Faculty of Engineering, Sivas University of Science and Technology, Sivas, Turkey.

Department of Chemical Engineering, Faculty of Engineering, Sivas University of Science and Technology, Sivas, Turkey.

出版信息

Int J Phytoremediation. 2025;27(2):206-214. doi: 10.1080/15226514.2024.2411248. Epub 2024 Oct 14.

Abstract

This study investigates the photocatalytic degradation of Procion Red MX-5B (PRM) using ZnO and Ni-doped ZnO catalysts derived from okra stalks through a green synthesis method. Various parameters, including hydrogen peroxide concentration (HPC), catalyst amount, nickel (Ni) doping amount, initial PRM concentration, and pH, are systematically studied to assess their impact on PRM degradation efficiency. The results reveal that both ZnO and Ni-doped ZnO catalysts exhibit promising photocatalytic activity, with the highest PRM degradation efficiency achieved at the following reaction conditions: 6 mM of HPC, 40 mg of Ni(7%):ZnO catalyst, 10 ppm initial PRM concentration, and pH = 6. Under these conditions, the Ni-doped ZnO catalyst demonstrated a degradation efficiency of 98.08% compared to 82.99% for the ZnO catalyst. The study highlights the potential of these catalysts for efficient organic pollutant removal and provides valuable insights into the factors influencing their photocatalytic performance.

摘要

本研究通过绿色合成法研究了以秋葵秸秆为原料制备的ZnO和Ni掺杂ZnO催化剂对活性艳红MX - 5B(PRM)的光催化降解作用。系统研究了包括过氧化氢浓度(HPC)、催化剂用量、镍(Ni)掺杂量、初始PRM浓度和pH值等各种参数,以评估它们对PRM降解效率的影响。结果表明,ZnO和Ni掺杂ZnO催化剂均表现出良好的光催化活性,在以下反应条件下可实现最高的PRM降解效率:6 mM的HPC、40 mg的Ni(7%):ZnO催化剂、10 ppm的初始PRM浓度和pH = 6。在此条件下,Ni掺杂ZnO催化剂的降解效率为98.08%,而ZnO催化剂为82.99%。该研究突出了这些催化剂在高效去除有机污染物方面的潜力,并为影响其光催化性能的因素提供了有价值的见解。

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