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一种姜黄素量子点掺杂的聚丙烯腈电纺纳米纤维涂层用于316L不锈钢,以提高其在海洋环境中的耐腐蚀性。

A curcumin quantum dot blended polyacrylonitrile electrospun nanofiber coating on 316 L SS for improved corrosion resistance in the marine environment.

作者信息

Badsha Iffath, Rasal Renjith Kumar, Taweepreda Wirach, Gangasalam Arthanareeswaran, Thiyagarajan Devasena

机构信息

Centre for Nanoscience and Technology, Anna University Chennai-600025 India

Polymer Science Program, Division of Physical Science, Faculty of Science, Prince of Songkla University Hat-Yai Songkhla 90110 Thailand.

出版信息

RSC Adv. 2024 Oct 11;14(44):32109-32125. doi: 10.1039/d4ra05075d. eCollection 2024 Oct 9.

DOI:10.1039/d4ra05075d
PMID:39399253
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11467652/
Abstract

Corrosion of 316 L SS is a significant global concern and recently polymeric nanofibers have been gaining attention for their potential in enhancing the corrosion resistance of metals. In this work, an electrospinning technique was deployed for the deposition of a curcumin quantum dot (CMQD) blended polyacrylonitrile (PAN) nanofibrous anticorrosive coating on 316 L SS. The optimized PAN-CMQD coated samples obtained from the weight loss studies were examined to assess their corrosion inhibition characteristics in 3.5 wt% NaCl electrolyte as the corrosion environment using potentiodynamic polarization and electrochemical impedance spectroscopy. The PAN-CMQD coated samples showed two-order reduction in compared to the uncoated 316 L SS. The results of the long-term analysis for 30 days revealed no significant changes in and values and no pit formation for PAN-CMQD coated samples, proving the longevity of the coating. Thus, this work will serve as a cost-effective futuristic strategy for the large-scale development of anticorrosive nanofibrous coatings for enhancing the corrosion resistance behavior of metals and alloys in various industrial sectors.

摘要

316L不锈钢的腐蚀是一个重大的全球问题,最近聚合物纳米纤维因其在提高金属耐腐蚀性方面的潜力而受到关注。在这项工作中,采用静电纺丝技术在316L不锈钢上沉积姜黄素量子点(CMQD)共混聚丙烯腈(PAN)纳米纤维防腐涂层。通过失重研究获得的优化PAN-CMQD涂层样品,使用动电位极化和电化学阻抗谱在3.5 wt% NaCl电解液作为腐蚀环境中评估其缓蚀特性。与未涂层的316L不锈钢相比,PAN-CMQD涂层样品的[具体指标]降低了两个数量级。30天的长期分析结果表明,PAN-CMQD涂层样品的[具体指标]和[具体指标]值没有显著变化,也没有点蚀形成,证明了涂层的耐久性。因此,这项工作将成为一种具有成本效益的未来策略,用于大规模开发防腐纳米纤维涂层,以提高各种工业领域中金属和合金的耐腐蚀性能。

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