Pivar Matej, Muck Deja
Faculty of Natural Sciences and Engineering, University of Ljubljana, Snežniška 5, 1000 Ljubljana, Slovenia.
Polymers (Basel). 2024 Sep 24;16(19):2685. doi: 10.3390/polym16192685.
The field of 3D and 4D printing is advancing rapidly, offering new ways to control the transformation of programmable 3D structures in response to external stimuli. This study examines the impact of 3D printing parameters, namely the UV ink thickness (applied using a UV inkjet printer on pre-3D-printed programmable structures) and thermal activation, on the dimensional and surface changes to high-stress (HS) and low-stress (LS) programmable samples and on print quality. The results indicate that HS samples shrink in the longitudinal direction, while expanding in terms of their height and width, whereas LS samples exhibit minimal dimensional changes due to lower programmed stress. The dynamic mechanical analysis shows that UV ink, particularly cyan and CMYK overprints, reduces the shrinkage in HS samples by acting as a resistive layer. Thicker ink films further reduce the dimensional changes in HS samples. Thermal activation increases the surface roughness of HS structures, leading to the wrinkling of UV ink films, while LS structures are less affected. The surface gloss decreases significantly in HS structures after UV ink application; however, thermal activation has little impact on LS structures. UV ink adhesion remains strong across both HS and LS samples, suggesting that UV inks are ideal for printing on programmable 3D structures, where the colour print quality and precise control of the shape transformation are crucial.
3D和4D打印领域正在迅速发展,为控制可编程3D结构响应外部刺激的转变提供了新方法。本研究考察了3D打印参数,即UV油墨厚度(使用UV喷墨打印机施加在预3D打印的可编程结构上)和热激活,对高应力(HS)和低应力(LS)可编程样品的尺寸和表面变化以及打印质量的影响。结果表明,HS样品在纵向收缩,而在高度和宽度方面膨胀,而LS样品由于较低的编程应力而表现出最小的尺寸变化。动态力学分析表明,UV油墨,特别是青色和CMYK叠印,通过作为电阻层来减少HS样品的收缩。较厚的油墨膜进一步减少了HS样品的尺寸变化。热激活增加了HS结构的表面粗糙度,导致UV油墨膜起皱,而LS结构受影响较小。在施加UV油墨后,HS结构的表面光泽度显著降低;然而,热激活对LS结构影响很小。UV油墨在HS和LS样品上的附着力都很强,这表明UV油墨非常适合在可编程3D结构上打印,在这种结构中,彩色打印质量和形状转变的精确控制至关重要。