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从鱼鳞和胶原蛋白中提取的生物废料填料对高密度聚氨酯泡沫塑料力学性能的比较

Comparison of Biowaste Fillers Extracted from Fish Scales and Collagen on the Mechanical Properties of High-Density Polyurethane Foams.

作者信息

Obiechefu Zodidi, Onwubu Stanley Chibuzor, Naidoo Deneshree, Mokhothu Thabang Hendrica, Mdluli Phumlane Selby

机构信息

Chemistry Department, Durban University of Technology (DUT), Durban 4001, South Africa.

Health Platform, Advanced Materials Division, Mintek, Randburg 2194, South Africa.

出版信息

Polymers (Basel). 2024 Oct 6;16(19):2825. doi: 10.3390/polym16192825.

Abstract

The utilization of biowaste fillers in the development of high-density polyurethane (PU) foams has gained significant attention due to environmental and economic benefits. This study investigates the mechanical properties of PU foams reinforced with biowaste fillers extracted from fish scales (FS) and fish scale-derived collagen (FSC). The fish scales and collagen were characterized for their composition and integrated into PU foams at various loadings. Mechanical properties such as tensile strength, hardness, and density were evaluated. ANOVA was used to analyze the mean values. Bonferroni tests were used to identify differences between the filler materials (α = 0.05). The tensile strength increases with an increase in filler content for both FS (59.48 Kpa) and FSC (65.43 Kpa). No differences were observed between FS and FSC in tensile strength. Significant differences were observed between the FS and FSC in both hardness and density ( < 0.001). The results demonstrated that both fillers enhanced the mechanical properties of PU foams, with collagen-reinforced foams showing superior performance. This suggests that collagen and fish scales can be effective biowaste fillers for developing environmentally friendly PU foams with enhanced mechanical properties.

摘要

由于环境和经济效益,在高密度聚氨酯(PU)泡沫塑料的开发中利用生物废料填料已引起了广泛关注。本研究调查了用从鱼鳞(FS)和鱼鳞衍生的胶原蛋白(FSC)中提取的生物废料填料增强的PU泡沫塑料的力学性能。对鱼鳞和胶原蛋白的成分进行了表征,并将其以不同的含量掺入PU泡沫塑料中。评估了诸如拉伸强度、硬度和密度等力学性能。采用方差分析来分析平均值。使用邦费罗尼检验来确定填料材料之间的差异(α = 0.05)。对于FS(59.48 Kpa)和FSC(65.43 Kpa),拉伸强度均随填料含量的增加而增加。在拉伸强度方面,未观察到FS和FSC之间存在差异。在硬度和密度方面,FS和FSC之间均观察到显著差异(< 0.001)。结果表明,两种填料均增强了PU泡沫塑料的力学性能,其中胶原蛋白增强的泡沫塑料表现出更优异的性能。这表明胶原蛋白和鱼鳞可以成为开发具有增强力学性能的环保型PU泡沫塑料的有效生物废料填料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/692f/11478490/4ccfda6f2888/polymers-16-02825-g001.jpg

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