填充核桃壳和矿物填料的硬质聚氨酯泡沫的阻燃性和热稳定性

Flame Retardancy and Thermal Stability of Rigid Polyurethane Foams Filled with Walnut Shells and Mineral Fillers.

作者信息

Makowska Sylwia, Miedzińska Karolina, Kairytė Agnė, Šeputytė-Jucikė Jurga, Strzelec Krzysztof

机构信息

Institute of Polymer & Dye Technology, Lodz University of Technology, 90-924 Lodz, Poland.

Civil Engineering Research Centre, Vilnius Gediminas Technical University, Saulėtekio Av. 11, 10223 Vilnius, Lithuania.

出版信息

Materials (Basel). 2024 Sep 21;17(18):4629. doi: 10.3390/ma17184629.

Abstract

Recently, the influence of the concept of environmental sustainability has increased, which includes environmentally friendly measures related to reducing the consumption of petrochemical fuels and converting post-production feedstocks into raw materials for the synthesis of polymeric materials, the addition of which would improve the performance of the final product. In this regard, the development of bio-based polyurethane foams can be carried out by, among other things, modifying polyurethane foams with vegetable or waste fillers. This paper investigates the possibility of using walnut shells (WS) and the mineral fillers vermiculite (V) and perlite (P) as a flame retardant to increase fire safety and thermal stability at higher temperatures. The effects of the fillers in amounts of 10 wt.% on selected properties of the polyurethane composites, such as rheological properties (dynamic viscosity and processing times), mechanical properties (compressive strength, flexural strength, and hardness), insulating properties (thermal conductivity), and flame retardant properties (e.g., ignition time, limiting oxygen index, and peak heat release) were investigated. It has been shown that polyurethane foams containing fillers have better performance properties compared to unmodified polyurethane foams.

摘要

近年来,环境可持续发展理念的影响力不断增强,这包括与减少石化燃料消耗以及将生产后原料转化为聚合物材料合成原料相关的环保措施,添加这些原料将改善最终产品的性能。在这方面,生物基聚氨酯泡沫的开发可以通过多种方式进行,例如用植物或废料填料对聚氨酯泡沫进行改性。本文研究了使用核桃壳(WS)以及矿物填料蛭石(V)和珍珠岩(P)作为阻燃剂以提高高温下的防火安全性和热稳定性的可能性。研究了含量为10 wt.% 的填料对聚氨酯复合材料选定性能的影响,如流变性能(动态粘度和加工时间)、机械性能(抗压强度、抗弯强度和硬度)、绝缘性能(热导率)以及阻燃性能(例如着火时间、极限氧指数和热释放峰值)。结果表明,与未改性的聚氨酯泡沫相比,含有填料的聚氨酯泡沫具有更好的性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4204/11433397/bf82be7d0b59/materials-17-04629-g001.jpg

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