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用于粘结剂喷射的淀粉基粘结剂的制备与表征

Preparation and characterization of starch-based binders for binder jetting.

作者信息

Jiang Hongtao, Yang Xinhao, Wang Hao

机构信息

School of Materials Science and Engineering, Shaanxi University of Science & Technology Xi'an 710021 China

出版信息

RSC Adv. 2024 Oct 15;14(44):32506-32516. doi: 10.1039/d4ra05411c. eCollection 2024 Oct 9.

Abstract

In recent years, binder jetting technology has made significant advances across industries, expanding the range of material options to meet diverse needs. Commonly used binders may leave residues during the sintering process, affecting surface quality and performance, and some may contain harmful substances. Therefore, there is a high demand for binders that are environmentally friendly and easy to remove. This study proposes to use sodium alginate and polyvinylpyrrolidone as additives to prepare starch-based inks that are both environmentally friendly and safe. The effects of additive composition, starch content, dispersant content, and dispersant ratio on the viscosity and stability of starch-based inks were studied. Through performance testing, the particle size, surface tension, rheological properties, and printability of inks with different components were demonstrated. The optimal ink formulation consists of 1 wt% starch and 0.3 wt% additives (30 wt% sodium alginate and 70 wt% PVP). The viscosity reaches 23 mPa s and the stability is excellent. The surface tension of the ink is 69.5 mN m, which is slightly higher than the surface tension requirements for the printhead. This article provides a new process route for binder jetting technology and lays the foundation for its application in green and environmental protection.

摘要

近年来,粘结剂喷射技术在各行业取得了重大进展,扩大了材料选择范围以满足多样化需求。常用粘结剂在烧结过程中可能会留下残留物,影响表面质量和性能,有些还可能含有有害物质。因此,对环保且易于去除的粘结剂有很高的需求。本研究提出使用海藻酸钠和聚乙烯吡咯烷酮作为添加剂来制备既环保又安全的淀粉基墨水。研究了添加剂组成、淀粉含量、分散剂含量和分散剂比例对淀粉基墨水粘度和稳定性的影响。通过性能测试,展示了不同成分墨水的粒径、表面张力、流变性能和可印刷性。最佳墨水配方由1 wt%的淀粉和0.3 wt%的添加剂(30 wt%的海藻酸钠和70 wt%的聚乙烯吡咯烷酮)组成。粘度达到23 mPa·s,稳定性极佳。墨水的表面张力为69.5 mN/m,略高于打印头的表面张力要求。本文为粘结剂喷射技术提供了一条新的工艺路线,并为其在绿色环保方面的应用奠定了基础。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5124/11474445/b0b992dba46f/d4ra05411c-f1.jpg

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