Jiang Pengcheng, Yang Yijing, Zhu Xun, Ye Dingding, Yang Yang, Wang Hong, An Liang, Fedorets Alexander A, Liao Qiang, Chen Rong, Nosonovsky Michael
Ministry of Education, Key Laboratory of Low-Grade Energy Utilization Technologies and Systems (Chongqing University), Chongqing 400030, China.
Institute of Engineering Thermophysics, School of Energy and Power Engineering, Chongqing University, Chongqing 400030, China.
J Phys Chem A. 2024 Oct 31;128(43):9447-9452. doi: 10.1021/acs.jpca.4c06443. Epub 2024 Oct 16.
It has been reported that the self-assembly pattern of light levitating droplet clusters above the hot gas-liquid interface is dependent on the quantity of droplets. However, the already-reported theoretical explanation of the quantity-dependent self-assembly pattern cannot work well when the quantity of the light levitating droplet exceeds 15. Herein, we propose a new theoretical perspective to understand the self-assembly of a light levitating droplet cluster by referring to the classical densest packing problem of identical rigid circles in a larger circle with the introduction of the minimum total potential energy principle. Amazingly, the theoretical results obtained by this new approach agree well with experimental results, even though the quantity of the light levitating droplet is up to 142. This study deepens our understanding of the quantity-dependent self-assembly pattern of the light levitating droplet clusters and provides significant inspiration for other analogous self-assembly phenomena.
据报道,热气 - 液界面上方光悬浮液滴簇的自组装模式取决于液滴的数量。然而,当光悬浮液滴的数量超过15时,已报道的关于数量依赖自组装模式的理论解释并不适用。在此,我们通过引入最小总势能原理,参考相同刚性圆在较大圆中的经典最密堆积问题,提出了一种新的理论视角来理解光悬浮液滴簇的自组装。令人惊讶的是,即使光悬浮液滴的数量高达142,这种新方法获得的理论结果与实验结果也吻合得很好。这项研究加深了我们对光悬浮液滴簇数量依赖自组装模式的理解,并为其他类似的自组装现象提供了重要的启示。