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小麦淀粉凝胶与菜籽油结合对3D打印精度的影响

Effect of 3D printing accuracy by wheat starch gel combined with canola oil.

作者信息

Bao Yanru, Yang Tao, Jiang Hao

机构信息

College of Food Science and Engineering, Northwest A & F University, Yangling 712100, China.

College of Food Science and Engineering, Northwest A & F University, Yangling 712100, China.

出版信息

Int J Biol Macromol. 2024 Dec;282(Pt 1):136614. doi: 10.1016/j.ijbiomac.2024.136614. Epub 2024 Oct 16.

DOI:10.1016/j.ijbiomac.2024.136614
PMID:39419147
Abstract

This study investigated the impact of canola oil (CO) on wheat starch (WS) in 3D printing, focusing on intermolecular interactions and gel characteristics. 3D printing performance, microstructure, rheology, texture, proton distribution, thermal properties, molecular structures, and crystal structure were used to analyze the properties of starch gels. The results showed that adding CO improved the similarity between printed products and their models, and facilitated smoother extrusion by enhancing the cohesiveness and adhesiveness of the WS-CO complex. Moreover, adding >6 % CO to the starch gels destabilized the 3D-printed structure, causing the top layer to collapse, which affected the aesthetics and printing accuracy. The WS-4%CO complex demonstrated superior printing performance and enhanced accuracy. FTIR (Fourier Transform Infrared) and NMR (Nuclear Magnetic Resonance) results indicated that the interaction between WS and CO involved non-covalent interactions, primarily hydrophobic interactions. SEM (scanning electron microscope) results further revealed the molecular structure, CO hindered the interaction between amylose and amylopectin, disrupting the ordered structure and increasing lamellar formation, thereby affecting the stability of the 3D printing structure. This experiment provides valuable insights for enriching the nutrition and improving the accuracy of 3D-printed food.

摘要

本研究调查了菜籽油(CO)对3D打印中小麦淀粉(WS)的影响,重点关注分子间相互作用和凝胶特性。利用3D打印性能、微观结构、流变学、质地、质子分布、热性能、分子结构和晶体结构来分析淀粉凝胶的性质。结果表明,添加CO提高了打印产品与其模型之间的相似度,并通过增强WS-CO复合物的内聚性和粘附性促进了更顺畅的挤出。此外,向淀粉凝胶中添加>6%的CO会破坏3D打印结构的稳定性,导致顶层塌陷,从而影响美观和打印精度。WS-4%CO复合物表现出优异的打印性能和更高的精度。傅里叶变换红外光谱(FTIR)和核磁共振(NMR)结果表明,WS和CO之间的相互作用涉及非共价相互作用,主要是疏水相互作用。扫描电子显微镜(SEM)结果进一步揭示了分子结构,CO阻碍了直链淀粉和支链淀粉之间的相互作用,破坏了有序结构并增加了层状结构的形成,从而影响了3D打印结构的稳定性。本实验为丰富3D打印食品的营养和提高其精度提供了有价值的见解。

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