金（I）/金（III）催化芳基碘化物的磺酰化反应用于合成各种功能化芳基砜
Au(I)/Au(III)-Catalyzed Sulfonylation of Aryl Iodides for the Synthesis of Various Functionalized Aryl Sulfones.
作者信息
Zhang Lizhu, Du Wenqian, Wu Jiawen, Yang Rongjie, E Xiu-Tian-Feng, Wang Junfeng, Xia Zhonghua
机构信息
School of Materials Science & Engineering, Beijing Institute of Technology, Beijing 100081, China.
College of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China.
出版信息
Org Lett. 2024 Nov 1;26(43):9413-9418. doi: 10.1021/acs.orglett.4c03724. Epub 2024 Oct 18.
A gold-catalyzed sulfonylation reaction of aryl iodides with different sodium sulfinates facilitated by the ligand-enabled Au(I)/Au(III) redox catalysis was developed. In the reaction of gold-catalyzed C-S coupling, a variety of functionalized sodium sulfinates, such as CF, CHF, CH, and alkyl groups, can react smoothly with aryl iodides to directly construct diversely functionalized aryl sulfones. This gold-catalyzed sulfonylation offers a complementary method for synthesizing functionalized aryl sulfones with electron-donating groups.
通过配体促进的Au(I)/Au(III)氧化还原催化作用，开发了一种金催化的芳基碘化物与不同亚磺酸钠的磺酰化反应。在金催化的C-S偶联反应中，各种官能化的亚磺酸钠，如CF、CHF、CH和烷基，都能与芳基碘化物顺利反应，直接构建出功能多样的芳基砜。这种金催化的磺酰化反应为合成带有供电子基团的功能化芳基砜提供了一种补充方法。
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