Zhang Tong, Wang Hongyue, Hu Hao, Li Wanxuan, Zhang Xindi, Zhang Xiangrong
School of Function Food and Wine, Shenyang Pharmaceutical University, 103 Wenhua Road, Shenyang 110016, China.
School of Traditional Chinese Materia Medica, Shenyang Pharmaceutical University, 103 Wenhua Road, Shenyang 110016, China.
Int J Biol Macromol. 2024 Dec;282(Pt 1):136740. doi: 10.1016/j.ijbiomac.2024.136740. Epub 2024 Oct 19.
The aim of this study is to fabricate a biodegradable film based on carboxymethyl cellulose and gellan gum (CMC/GG) with the honokiol/β-cyclodextrin inclusion complex (HNK/β-CD). The HNK/β-CD was prepared by freeze-drying and its physicochemical properties were investigated. Then HNK/β-CD was added to CMC/GG solution to form CMC/GG honokiol inclusion complex (HIC) composite film by the casting method. The physicochemical properties, antioxidant and antibacterial effects, and strawberry preservation function were investigated. The composite film with 0.18 % inclusion complex (CMC/GG/0.18 % HIC) was found to be the optimal formulation. The film had a tensile strength of 8.20 MPa and an elongation at break of 115.17 % with water vapor permeability of 0.48 g·mm·(cm·h·KPa). The increase of HNK/β-CD content yielded lower optical transmittance and water content of CMC/GG/HIC composite film, while improved the hydrophilicity value. The 2,2-diphenyl-1-picrylhydrazyl radical and 2,2'-azinobis-(3-ethylbenzthiazoline-6-sulphonate) scavenging capacities of CMC/GG/0.18 % HIC composite film were 80.83 % and 53.10 % respectively. CMC/GG/HIC composite film was bacteriostatic against Staphylococcus aureus and Candida albicans but not against Escherichia coli and Aspergillus niger. Packing strawberries with the optimized composite film can retain the appearance, titratable acidity and vitamin C content of strawberries, which was better than the commercially fresh-keeping film control group. The CMC/GG/HIC composite film overcame the shortcomings of a single material, and gained importance in food packaging applications.
本研究的目的是制备一种基于羧甲基纤维素和结冷胶(CMC/GG)并含有厚朴酚/β-环糊精包合物(HNK/β-CD)的可生物降解薄膜。通过冷冻干燥制备了HNK/β-CD,并对其理化性质进行了研究。然后将HNK/β-CD添加到CMC/GG溶液中,采用流延法形成CMC/GG厚朴酚包合物(HIC)复合薄膜。研究了该复合薄膜的理化性质、抗氧化和抗菌效果以及草莓保鲜功能。发现含有0.18%包合物(CMC/GG/0.18%HIC)的复合薄膜为最佳配方。该薄膜的拉伸强度为8.20MPa,断裂伸长率为115.17%,水蒸气透过率为0.48g·mm·(cm·h·KPa)。HNK/β-CD含量的增加导致CMC/GG/HIC复合薄膜的透光率和含水量降低,同时提高了亲水性值。CMC/GG/0.18%HIC复合薄膜对2,2-二苯基-1-苦基肼自由基和2,2'-偶氮二异丁基脒二盐酸盐的清除能力分别为80.83%和53.10%。CMC/GG/HIC复合薄膜对金黄色葡萄球菌和白色念珠菌有抑菌作用,但对大肠杆菌和黑曲霉没有抑菌作用。用优化后的复合薄膜包装草莓可以保持草莓的外观、可滴定酸度和维生素C含量,优于市售保鲜薄膜对照组。CMC/GG/HIC复合薄膜克服了单一材料的缺点,在食品包装应用中具有重要意义。