Wang Zean, Yang Jianjun, Zhai Yu, Chen Jibin, Pei Houchang, Sun Liangbo, Liu Hao
School of Mechanical Engineering, Wuhan Polytechnic University Wuhan 430023 China
State Key Laboratory of Coal Combustion, School of Energy and Power Engineering, Huazhong University of Science and Technology Wuhan 430074 China.
RSC Adv. 2024 Oct 21;14(45):33191-33197. doi: 10.1039/d4ra03590a. eCollection 2024 Oct 17.
Waste tobacco stalk is blended with graphite carbon to form a composite carbon source, which is a promising external heating system for heat-not-burn tobaccos. In the current work, the effects of tobacco stalk amounts and the catalyst KCO on the co-combustion characteristics (, the ignition temperature, burnout temperature, ) of graphite carbon were investigated. As a result, the ignition temperatures of the blend were determined by the tobacco straw, while the burnout temperature of the samples was reduced by approximately 60 °C due to the addition of a tobacco stalk. After the addition of KCO, the ignition temperatures of the mixture were further decreased by 2-7 °C since the ignition temperature of the tobacco stalk was difficult to further reduce after KCO addition. Meanwhile, the burnout temperature can be reduced by 76-106 °C because the presence of KCO can significantly improve the combustion of graphite carbon. In addition, the kinetic analysis revealed that during the release of volatile matter, the oxidation process accords with the first-order kinetic model, while in the combustion process of mixed carbon source, the combustion process can be described by the third-order kinetic model.
废弃烟梗与石墨碳混合形成复合碳源,这是一种很有前景的加热不燃烧烟草的外部加热系统。在当前工作中,研究了烟梗用量和催化剂碳酸钾对石墨碳共燃烧特性(着火温度、 burnout温度等)的影响。结果表明,混合物的着火温度由烟梗决定,而由于添加了烟梗,样品的 burnout温度降低了约60℃。添加碳酸钾后,混合物的着火温度进一步降低了2 - 7℃,因为添加碳酸钾后烟梗的着火温度难以进一步降低。同时,burnout温度可降低76 - 106℃,因为碳酸钾的存在可显著改善石墨碳的燃烧。此外,动力学分析表明,在挥发物释放过程中,氧化过程符合一级动力学模型,而在混合碳源燃烧过程中,燃烧过程可用三级动力学模型描述。