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近红外响应光催化剂在环境修复和能量转换中的应用:综述。

Near-infrared responsive photocatalysts for environmental remediation and energy conversion: A review.

机构信息

Hubei Key Laboratory of Mineral Resources Processing and Environment, Key Laboratory of Green Utilization of Critical Non-metallic Mineral Resources, Ministry of Education, State Key Laboratory of Silicate Materials for Architectures, Wuhan University of Technology, Wuhan, 430000, China.

Department of Unconventional Catalytic Processes, Boreskov Institute of Catalysis, Novosibirsk, 630090, Russia.

出版信息

Chemosphere. 2024 Nov;367:143599. doi: 10.1016/j.chemosphere.2024.143599. Epub 2024 Oct 22.

Abstract

Photocatalytic technology provides a vital pathway for the sustainable and efficient removal of environmental pollutants and energy conversion. However, enhancing the near-infrared (NIR) light absorption and utilization capabilities of photocatalysts has remained a significant challenge in this field. This paper presents a comprehensive review of recent developments in NIR-responsive photocatalysts. It systematically outlines strategies for improving the NIR light absorption capacity of photocatalysts, including doping engineering, upconversion, and plasmonic resonance effects. The discussion then progresses to cover advancements in NIR-responsive photocatalytic materials, highlighting the relationship between their unique physicochemical properties and corresponding modification strategies. Furthermore, the review explores the applications and mechanisms of various NIR-responsive photocatalysts in pollutant degradation, CO reduction, volatile organic compounds removal, and the green synthesis of H and HO. Finally, the paper addresses the challenges faced in developing NIR-responsive photocatalysts and their broader applications, proposing future research directions to mitigate these existing barriers.

摘要

光催化技术为环境污染物的可持续和高效去除以及能源转化提供了重要途径。然而,提高光催化剂对近红外(NIR)光的吸收和利用能力仍然是该领域的一个重大挑战。本文对 NIR 响应型光催化剂的最新发展进行了全面综述。它系统地概述了提高光催化剂 NIR 光吸收能力的策略,包括掺杂工程、上转换和等离子体共振效应。然后讨论了 NIR 响应型光催化材料的进展,强调了它们独特的物理化学性质与相应的改性策略之间的关系。此外,本综述还探讨了各种 NIR 响应型光催化剂在污染物降解、CO 还原、挥发性有机化合物去除和 H 和 HO 的绿色合成中的应用和机制。最后,本文讨论了开发 NIR 响应型光催化剂及其更广泛应用所面临的挑战,并提出了未来的研究方向,以减轻这些现有障碍。

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