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评估外卖容器中微塑料的排放:跨多种暴露场景的微拉曼方法。

Evaluating microplastic emission from takeaway containers: A Micro-Raman approach across diverse exposure scenarios.

机构信息

Department of Pharmacy, University of Salerno, Via Giovanni Paolo II, SA, Fisciano 13284084, Italy.

Department of Agricultural, Environmental and Food Sciences (DiAAA), University of Molise, Campobasso 86100, Italy.

出版信息

Food Chem. 2025 Feb 1;464(Pt 2):141716. doi: 10.1016/j.foodchem.2024.141716. Epub 2024 Oct 18.

Abstract

Based on inconsistencies observed in literature regarding microplastic levels released by takeaway plastic containers, this study investigates the release from takeaway containers composed of polypropylene (PP), polystyrene (PS), and polyethylene terephthalate (PET). To simulate real-world conditions, experiments were conducted using Milli-Q water at room temperature, 100 °C, and at pH 4.5. Containers were subjected to 20-min exposure with agitation, and microplastics were quantified via optical microscopy, with micro-Raman spectroscopy to confirm the particle polymeric nature. The results indicate that PET and PS containers released microplastic in varying quantities: 9 and 1 at room temperature, 7 and 3 in acidified water, and 17 and 30 at 100 °C, respectively. The particle sizes ranged between 13 and 32 μm. Notably, no microplastics were detected from PP containers under any tested conditions. This study underscores the significant release of microplastics from PET and PS containers, particularly at elevated temperatures, suggesting that PP may represent a safer alternative.

摘要

基于文献中关于外卖塑料容器释放的微塑料水平的不一致性,本研究调查了由聚丙烯(PP)、聚苯乙烯(PS)和聚对苯二甲酸乙二醇酯(PET)制成的外卖容器的释放情况。为了模拟实际情况,使用 Milli-Q 水在室温、100°C 和 pH 值 4.5 下进行了实验。将容器暴露于搅拌 20 分钟,并通过光学显微镜定量微塑料,并用微拉曼光谱法确认颗粒的聚合物性质。结果表明,PET 和 PS 容器以不同的量释放微塑料:在室温下分别为 9 和 1,在酸化水中分别为 7 和 3,在 100°C 下分别为 17 和 30。颗粒尺寸在 13 和 32 μm 之间。值得注意的是,在任何测试条件下,PP 容器均未检测到微塑料。本研究强调了 PET 和 PS 容器中微塑料的大量释放,特别是在高温下,表明 PP 可能是一种更安全的选择。

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