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揭示内在钾/钙元素对钠离子电池用生物废弃物衍生硬碳的结构影响机制。

Revealing the structural influence mechanism of intrinsic potassium/calcium elements on bio-waste-derived hard carbon for sodium-ion batteries.

作者信息

Zhang Yinghao, Wu Chun, Chen Qinghang, Li Chuangchuang, Huang Wenjie, Wen Qianxiong, He Xiang-Xi, Wu Xingqiao, Chou Shu-Lei

机构信息

Institute for Carbon Neutralization Technology, College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou, Zhejiang 325035, China.

Wenzhou Key Laboratory of Sodium-Ion Batteries, Wenzhou University Technology Innovation Institute for Carbon Neutralization, Wenzhou, Zhejiang 325035, China.

出版信息

Chem Commun (Camb). 2024 Nov 12;60(91):13380-13383. doi: 10.1039/d4cc03546a.

DOI:10.1039/d4cc03546a
PMID:39449658
Abstract

Waste gourd shells enriched with ash-forming elements are selected as raw materials in this paper, discovering that the K and Ca compounds in the precursor not only exhibit the ability of self-forming pores, but also demonstrate catalytic graphitization of the hard carbon during the pyrolysis procedure.

摘要

本文选用富含成灰元素的冬瓜壳作为原料,发现前驱体中的钾和钙化合物不仅具有自形成孔隙的能力,而且在热解过程中还表现出对硬碳的催化石墨化作用。

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引用本文的文献

1
Potassium escaping balances the degree of graphitization and pore channel structure in hard carbon to boost plateau sodium storage capacity.钾的脱出平衡了硬碳中的石墨化程度和孔道结构,以提高平台期钠存储容量。
Chem Sci. 2024 Dec 9;16(3):1179-1188. doi: 10.1039/d4sc04584j. eCollection 2025 Jan 15.