Highly efficient pure organic near-ultraviolet (NUV) electro-fluorescent materials with high electron mobility and improved hole mobility.

The lack of blue-emissive materials with high efficiency and excellent color purity commonly represents a pivotal obstacle in the development of organic light-emitting diodes (OLEDs). In this work, two blue to near-ultraviolet (NUV) donor-π-acceptor (D-π-A) emitters based on a fluorene π-bridge, 9-PCZCFTZ and 3-PCZCFTZ, are thus designed and synthesized, and non-doped devices derived from these two materials exhibit electroluminescence (EL) emission peaks at 404 nm and 417 nm, respectively. Interestingly, due to the specific stacking, a phenomenon appears in both materials in which the mobility of the electron is much higher than that of the hole, prompting us to use host doping to increase the hole mobilities, which ultimately leads to excellent OLED performances. As a result, the maximum external quantum efficiency (EQE) values of 9-PCZCFTZ and 3-PCZCFTZ in the doped devices reach as high as 14.5% and 10.8% respectively. Notably, both OLEDs show high blue purity very close to the BT.2020 standard.