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用于生物医学植入物的增材制造3D多孔激光粉末床熔融316L不锈钢结构在模拟体液中的力学和腐蚀行为

Mechanical and Corrosion Behaviour in Simulated Body Fluid of As-Fabricated 3D Porous L-PBF 316L Stainless Steel Structures for Biomedical Implants.

作者信息

Nogueira Pedro, Magrinho João, Reis Luis, de Deus Augusto Moita, Silva Maria Beatriz, Lopes Pedro, Oliveira Luís, Castela António, Cláudio Ricardo, Alves Jorge L, Vaz Maria Fátima, Carmezim Maria, Santos Catarina

机构信息

IDMEC-Institute of Mechanical Engineering, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal.

CeFEMA-Center of Physics and Engineering of Advanced Materials, Instituto Superior Técnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal.

出版信息

J Funct Biomater. 2024 Oct 21;15(10):313. doi: 10.3390/jfb15100313.

Abstract

Laser powder bed fusion (L-PBF) is one of the most promising additive manufacturing technologies for creating customised 316L Stainless Steel (SS) implants with biomimetic characteristics, controlled porosity, and optimal structural and functional properties. However, the behaviour of as-fabricated 3D 316L SS structures without any surface finishing in environments that simulate body fluids remains largely unknown. To address this knowledge gap, the present study investigates the surface characteristics, the internal porosity, the corrosion in simulated body fluid (SBF), and the mechanical properties of as-fabricated 316L SS structures manufactured by L-PBF with rhombitruncated cuboctahedron (RTCO) unit cells with two distinct relative densities (10 and 35%). The microstructural analysis confirmed that the RTCO structure has a pure austenitic phase with a roughness of ~20 µm and a fine cellular morphology. The micro-CT revealed the presence of keyholes and a lack of fusion pores in both RTCO structures. Despite the difference in the internal porosity, the mechanical properties of both structures remain within the range of bone tissue and in line with the Gibson and Ashby model. Additionally, the as-fabricated RTCO structures demonstrated passive corrosion behaviour in the SBF solution. Thus, as-fabricated porous structures are promising biomaterials for implants due to their suitable surface roughness, mechanical properties, and corrosion resistance, facilitating bone tissue growth.

摘要

激光粉末床熔融(L-PBF)是最具前景的增材制造技术之一,可用于制造具有仿生特性、可控孔隙率以及最佳结构和功能特性的定制316L不锈钢(SS)植入物。然而,在模拟体液的环境中,未经任何表面处理的3D打印316L SS结构的行为在很大程度上仍不为人知。为填补这一知识空白,本研究调查了由L-PBF制造的具有两种不同相对密度(10%和35%)的截顶菱形立方八面体(RTCO)晶胞的316L SS结构的表面特性、内部孔隙率、在模拟体液(SBF)中的腐蚀情况以及力学性能。微观结构分析证实,RTCO结构具有纯奥氏体相,粗糙度约为20 µm,且具有精细的胞状形态。微观计算机断层扫描(micro-CT)显示,两种RTCO结构中均存在匙孔和未熔合孔隙。尽管内部孔隙率存在差异,但两种结构的力学性能均保持在骨组织的范围内,并且符合吉布森和阿什比模型。此外,3D打印的RTCO结构在SBF溶液中表现出钝化腐蚀行为。因此,3D打印的多孔结构因其合适的表面粗糙度、力学性能和耐腐蚀性,有利于骨组织生长,是很有前景的植入生物材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c29e/11508611/3716322c01e9/jfb-15-00313-g001.jpg

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