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镍网增强超声辅助铜/锡58铋/铜接头性能:实验与第一性原理计算

Ni mesh-reinforced ultrasonic-assisted Cu/Sn58Bi/Cu joint performance: Experiments and first-principles calculations.

作者信息

Huang Xi, Zhang Liang, Chen Yu-Hao, Sun Lei, Yu Xin-Quan, Lu Quan-Bin

机构信息

School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361000, China.

School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361000, China.

出版信息

Ultrason Sonochem. 2024 Dec;111:107119. doi: 10.1016/j.ultsonch.2024.107119. Epub 2024 Oct 21.

Abstract

The Ni mesh was incorporated into the Cu/Sn58Bi/Cu bonding as a reinforcing skeleton to achieve an enhancement effect analogous to steel reinforcement in concrete. Ultrasonic-assisted soldering (UAS) improved the metallurgical bond among the solder, Ni mesh, and substrate. It facilitated the formation of (Cu, Ni)Sn intermetallic compounds (IMCs) layers, increasing the joint strength. Observations indicated that ultrasonic treatment effectively refined the (Cu, Ni)Sn grains and induced a uniform preferred orientation of β-Sn and Bi grains in the joint matrix adjacent to the Ni mesh. The shear strength of the joint reached 72.23 MPa when the ultrasonic application was sustained for 15 s, achieving the fabrication of a high-strength point with low energy consumption. First-principles calculations have confirmed that changes in the Ni content within (Cu, Ni)Sn IMCs improved the stability of the crystal structure. Furthermore, the variations in content could potentially improve the mechanical and electrical properties of the (Cu, Ni)Sn. Enhancements in ultrasonic efficiency and the reinforcement of IMC structures offer new avenues for research in green and high-performance electronic packaging material joining technologies.

摘要

将镍网作为增强骨架融入铜/锡58铋/铜键合中,以实现类似于混凝土中钢筋增强的效果。超声辅助焊接(UAS)改善了焊料、镍网和基板之间的冶金结合。它促进了(铜,镍)锡金属间化合物(IMC)层的形成,提高了接头强度。观察表明,超声处理有效地细化了(铜,镍)锡晶粒,并在与镍网相邻的接头基体中诱导了β-锡和铋晶粒的均匀择优取向。当超声作用持续15秒时,接头的剪切强度达到72.23MPa,实现了低能耗的高强度焊点制造。第一性原理计算证实,(铜,镍)锡金属间化合物中镍含量的变化提高了晶体结构的稳定性。此外,含量的变化可能会改善(铜,镍)锡的力学和电学性能。超声效率的提高和IMC结构的增强为绿色高性能电子封装材料连接技术的研究提供了新的途径。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/879a/11539480/d5dc34377d29/gr1.jpg

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