Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People's Republic of China, Nanjing 210042, China.
Nanjing Institute of Environmental Sciences, Ministry of Ecology and Environment of the People's Republic of China, Nanjing 210042, China.
Waste Manag. 2024 Dec 15;190:538-547. doi: 10.1016/j.wasman.2024.10.012. Epub 2024 Oct 24.
The escalating global issue of soil pollution by heavy metals, particularly incinerated municipal solid waste fly ash (IMSWFA), necessitates effective remediation strategies. The prevailing approach for safely disposing and utilization of IMSWFA involves high-temperature sintering. In this work, we propose a cost-effective method to produce ceramsites by utilizing IMSWFA, municipal sludge (MS), contaminated soil (CS), and iron tail slag (ITS). After conducting a comprehensive analysis and comparison of outcomes obtained from orthogonal experiments and single-factor experiments, it was determined that the optimal preparation conditions for achieving desirable results are preheating at a temperature of 400 °C for 15 min followed by sintering at a temperature of 1150 °C for 10 min. The optimal ratio of raw materials for ceramsites is 15 % IMSWFA, 15 % MS, 58 % CS, and 12 % ITS. The ceramsites, prepared in accordance with the specified process and raw material ratio, exhibit remarkable properties including robust stability, minimal water absorption, reduced weight, and elevated cylindrical compressive strength. The ceramsites demonstrate an exceptionally high heavy metal loss ratio ranging from 91 % to 100 %, while exhibiting significantly lower leaching quantities of these metals compared to the raw materials. Additionally, aging tests of ceramsites were performed under UV light and acid/alkaline etching to simulate the real-world environment. This work can be utilized to investigate the long-term environmental impact of ceramsites derived from municipal solid waste (MSW), thereby making a valuable contribution to the advancement of solid waste management technology.
重金属污染土壤问题日益严峻,尤其是焚烧城市生活垃圾飞灰(IMSWFA)。因此,需要采取有效的修复策略。目前,高温烧结法是安全处置和利用 IMSWFA 的主要方法。本文提出了一种利用 IMSWFA、城市污泥(MS)、污染土壤(CS)和铁尾矿渣(ITS)制备陶粒的经济实用方法。通过对正交实验和单因素实验结果进行综合分析和比较,确定了获得理想结果的最佳制备条件为:预热温度 400°C、预热时间 15min,烧结温度 1150°C、烧结时间 10min。陶粒的最佳原料配比为 IMSWFA15%、MS15%、CS58%、ITS12%。按照规定的工艺和原料配比制备的陶粒具有稳定性好、吸水率低、容重小、圆柱抗压强度高的特点。重金属浸出量低,重金属浸出率高达 91%~100%。同时,对陶粒进行了 UV 老化和酸/碱蚀刻老化实验,以模拟真实环境。本研究可以为城市固体废物(MSW)衍生陶粒的长期环境影响研究提供参考,为固体废物管理技术的发展做出贡献。