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基于ABS/多壁碳纳米管纳米复合材料的3D打印压力传感器的各向异性压阻响应

Anisotropic piezoresistive response of 3D-printed pressure sensor based on ABS/MWCNT nanocomposite.

作者信息

Quaresma Luciano J B, Oliveira Dhonata S C, Dias Rosielem S, Alves Kelly C, de Barros Luiz G D, Pessin Gustavo, Sinatora Amilton, Paraguassu Waldeci, Dos Reis Marcos A L

机构信息

Graduate Program in Materials Science and Engineering, Federal University of Pará, Ananindeua, PA, Brazil.

3D Nanostructuring Laboratory, Federal University of Pará, Belém, PA, Brazil.

出版信息

Sci Rep. 2024 Oct 25;14(1):25297. doi: 10.1038/s41598-024-76028-2.


DOI:10.1038/s41598-024-76028-2
PMID:39455667
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11511984/
Abstract

Nanocomposites based on carbon nanotubes (CNTs) are suitable for sensors, due to matrix ability to incorporate nanotube properties. Thus, we developed a low-cost, nanostructured poly(acrylonitrile-butadiene-styrene) (ABS) polymer piezoresistive sensor produced by additive manufacturing. For this, solution layers of acetone, dimethylformamide and CNTs functionalized with carboxylic acid were pulverized on an ABS substrate using an aerograph. Electrical characterization revealed an anisotropic piezoresistive response of the material, induced by the printing lines direction. Field Emission Gun-Scanning Electron Microscopy showed the nanostructured film spreading after five layers of CNTs as well as the random entanglement of nanotubes on parallel and perpendicular 3D-printed ABS substrates. Raman spectroscopy indicated compression and p-type doping of CNTs in interaction with the polymer, as seen mainly by the blueshift of the G and 2D subbands. The results show that the material is promising for pressure sensors, with potential applications in robotic haptic feedback systems.

摘要

基于碳纳米管(CNT)的纳米复合材料适用于传感器,这是因为基体能够融合纳米管的特性。因此,我们开发了一种通过增材制造生产的低成本、纳米结构的聚(丙烯腈-丁二烯-苯乙烯)(ABS)聚合物压阻传感器。为此,使用喷枪将丙酮、二甲基甲酰胺和用羧酸官能化的碳纳米管的溶液层喷在ABS基板上。电学表征揭示了由印刷线路方向引起的材料各向异性压阻响应。场发射枪扫描电子显微镜显示,在五层碳纳米管之后纳米结构薄膜得以铺展,以及纳米管在平行和垂直的3D打印ABS基板上的随机缠结。拉曼光谱表明,碳纳米管与聚合物相互作用时发生了压缩和p型掺杂,主要表现为G和2D子带的蓝移。结果表明,该材料在压力传感器方面具有应用前景,在机器人触觉反馈系统中具有潜在应用价值。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/b980eb2e2afa/41598_2024_76028_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/568ddddfa673/41598_2024_76028_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/a09be85d94f8/41598_2024_76028_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/1954ac9dd9c9/41598_2024_76028_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/43256a2e7dca/41598_2024_76028_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/b980eb2e2afa/41598_2024_76028_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/568ddddfa673/41598_2024_76028_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/a09be85d94f8/41598_2024_76028_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/1954ac9dd9c9/41598_2024_76028_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/43256a2e7dca/41598_2024_76028_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ed3d/11511984/b980eb2e2afa/41598_2024_76028_Fig5_HTML.jpg

相似文献

[1]
Anisotropic piezoresistive response of 3D-printed pressure sensor based on ABS/MWCNT nanocomposite.

Sci Rep. 2024-10-25

[2]
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[7]
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[8]
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[9]
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[10]
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本文引用的文献

[1]
A 30-Year Review on Nanocomposites: Comprehensive Bibliometric Insights into Microstructural, Electrical, and Mechanical Properties Assisted by Artificial Intelligence.

Materials (Basel). 2024-2-27

[2]
The Relevant Approaches for Aligning Carbon Nanotubes.

Micromachines (Basel). 2022-10-30

[3]
Functionalized carbon nanotubes: synthesis, properties and applications in water purification, drug delivery, and material and biomedical sciences.

Nanoscale Adv. 2021-8-9

[4]
Soft CNT-Polymer Composites for High Pressure Sensors.

Sensors (Basel). 2022-7-14

[5]
Joule-Heating Effect of Thin Films with Carbon-Based Nanomaterials.

Materials (Basel). 2022-6-18

[6]
Self-Calibration Technique with Lightweight Algorithm for Thermal Drift Compensation in MEMS Accelerometers.

Micromachines (Basel). 2022-4-8

[7]
Do Microplastics Enter Our Food Chain Via Root Vegetables? A Raman Based Spectroscopic Study on .

Materials (Basel). 2021-4-30

[8]
Carbon Nanomaterials: Synthesis, Functionalization and Sensing Applications.

Nanomaterials (Basel). 2021-4-9

[9]
Matching Rheology, Conductivity and Joule Effect in PU/CNT Nanocomposites.

Polymers (Basel). 2021-3-19

[10]
Review on Conductive Polymer/CNTs Nanocomposites Based Flexible and Stretchable Strain and Pressure Sensors.

Sensors (Basel). 2021-1-6

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