Gu Yuqi, Shi Lifang, Wu Jianhua, Hu Sheng, Shang Yuqian, Hassan Muhammad, Zhao Chao
College of Optical, Mechanical and Electrical Engineering, Zhejiang A&F University, Hangzhou 311300, China.
Panzhihua Academy of Agriculture and Forestry Sciences, Panzhihua 617061, China.
Foods. 2024 Oct 12;13(20):3249. doi: 10.3390/foods13203249.
Acid value (AV) serves as an important indicator to assess the quality of oil, which can be used to judge the deterioration of edible oil. In order to realize the quantitative prediction of the AV of camellia seed oil, which was made from camellia oleifolia, hyperspectral data of 168 camellia seed oil samples were collected using a hyperspectral imaging system, which were related to their AV content measured via classical chemical titration. On the basis of hyperspectral full wavelengths, characteristic wavelengths, and fusing spectral and image features, the quantitative prediction AV models for camellia seed oil were established. The results demonstrating the 2Der-SPA-GLCM-PLSR model fusing spectral and image features stood out as the optimal choices for the AV prediction of camellia seed oil, with the correlation coefficient of calibration set (Rc2) and the correlation coefficient of prediction set (Rp2) at 0.9698 and 0.9581, respectively. Compared with those of 2Der-SPA-PLSR, the Rc2 and Rp2 were improved by 2.11% and 2.57%, respectively. Compared with those of 2Der-PLSR, the Rc2 and Rp2 were improved by 5.02% and 5.31%, respectively. Compared with the model based on original spectrum, the Rc2 and Rp2 were improved by 32.63% and 40.11%, respectively. After spectral preprocessing, characteristic wavelength selection, and fusing spectral and image features, the correlation coefficient of the optimal AV prediction model was continuously improved, while the root mean square error was continuously decreased. The research demonstrated that hyperspectral imaging technology could precisely and quantitatively predict the AV of camellia seed oil and also provide a new environmental method for detecting the AV of other edible oils, which is conducive to sustainable development.
酸值(AV)是评估油脂质量的重要指标,可用于判断食用油的劣变情况。为了实现对由油茶籽制取的茶籽油酸值的定量预测,使用高光谱成像系统采集了168个茶籽油样品的高光谱数据,并通过经典化学滴定法测定了其酸值含量。基于高光谱全波长、特征波长以及融合光谱和图像特征,建立了茶籽油酸值定量预测模型。结果表明,融合光谱和图像特征的二维连续投影算法-灰度共生矩阵-偏最小二乘回归(2Der-SPA-GLCM-PLSR)模型是茶籽油酸值预测的最佳选择,校正集相关系数(Rc2)和预测集相关系数(Rp2)分别为0.9698和0.9581。与二维连续投影算法-偏最小二乘回归(2Der-SPA-PLSR)模型相比,Rc2和Rp2分别提高了2.11%和2.57%。与二维偏最小二乘回归(2Der-PLSR)模型相比,Rc2和Rp2分别提高了5.02%和5.31%。与基于原始光谱的模型相比,Rc2和Rp2分别提高了32.63%和40.11%。经过光谱预处理、特征波长选择以及融合光谱和图像特征后,最佳酸值预测模型的相关系数不断提高,而均方根误差不断降低。研究表明,高光谱成像技术能够精确、定量地预测茶籽油的酸值,也为检测其他食用油的酸值提供了一种新的无损检测方法,有利于可持续发展。