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使用含CHNaO的NaNO混合电解液,通过带有滚印掩膜在GH4169合金上进行微坑阵列的电化学加工。

Electrochemical Machining of Micro-Pit Arrays on a GH4169 Alloy with a Roll-Print Mask Using a CHNaO-Containing NaNO Mixed Electrolyte.

作者信息

Qin Ge, Li Shiwei, Li Meng, Peng Haoyu, Niu Shen, Li Xinchao, Liu Huan, Yan Liang, Ming Pingmei

机构信息

School of Mechanical and Power Engineering, Henan Polytechnic University, Jiaozuo 454000, China.

出版信息

Micromachines (Basel). 2024 Oct 12;15(10):1253. doi: 10.3390/mi15101253.

DOI:10.3390/mi15101253
PMID:39459127
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11509597/
Abstract

GH4169 alloy, a nickel-based superalloy known for its excellent high temperature resistance, corrosion resistance, mechanical properties, and high-temperature tribological properties, is widely used in industrial applications, such as in gas turbines for space shuttles and rocket engines. This study addresses the issue of electrolyte product residue in the electrochemical machining process of a GH4169 alloy by utilizing a CHNaO-containing NaNO new mixed electrolyte. Comparative investigations of the electrochemical behavior and electrolyte product removal mechanisms at different concentrations of CHNaO additive in NaNO solutions were conducted. The effects of additives, applied voltage, and the rotating speed of the cathode tool on the processing performance of micro-pit arrays on a GH4169 alloy were analyzed. The results indicate that the mixed solution containing CHNaO significantly improves the localization and geometric morphology of the micro-pits compared to a single NaNO solution. The optimal electrochemical machining parameters were identified as 0.5 wt% CHNaO + 10 wt% NaNO mixed electrolyte, 12 V applied voltage, and 0.1 r/min rotating speed of the cathode tool. Under these conditions, high-quality micro-pit arrays with an average diameter of 405.85 μm, an average depth of 87.5 μm, and an etch factor (EF) of 1.67 were successfully fabricated, exhibiting excellent morphology, localization, and consistency.

摘要

GH4169合金是一种镍基高温合金,以其优异的耐高温性、耐腐蚀性、机械性能和高温摩擦学性能而闻名,广泛应用于工业领域,如航天飞机的燃气轮机和火箭发动机。本研究通过使用含CHNaO的NaNO新型混合电解液,解决了GH4169合金电化学加工过程中电解液产物残留的问题。对不同浓度的CHNaO添加剂在NaNO溶液中的电化学行为和电解液产物去除机制进行了对比研究。分析了添加剂、施加电压和阴极工具转速对GH4169合金微坑阵列加工性能的影响。结果表明,与单一NaNO溶液相比,含CHNaO的混合溶液显著改善了微坑的局部化和几何形态。确定最佳电化学加工参数为0.5 wt% CHNaO + 10 wt% NaNO混合电解液、12 V施加电压和0.1 r/min阴极工具转速。在此条件下,成功制备出平均直径为405.85μm、平均深度为87.5μm、蚀刻因子(EF)为1.67的高质量微坑阵列,具有优异的形态、局部化和一致性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/dcd6a8b3a6ff/micromachines-15-01253-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/b637cbca1fcb/micromachines-15-01253-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/de03f6beac46/micromachines-15-01253-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/ab7028438253/micromachines-15-01253-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/610d046e2b65/micromachines-15-01253-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/42d80c553378/micromachines-15-01253-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/3417b6fa7c75/micromachines-15-01253-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/7bfd2f288348/micromachines-15-01253-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/aae33fd5e764/micromachines-15-01253-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/be2e4cc4ff5c/micromachines-15-01253-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/933a2d3d9406/micromachines-15-01253-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/dcd6a8b3a6ff/micromachines-15-01253-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/b637cbca1fcb/micromachines-15-01253-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/de03f6beac46/micromachines-15-01253-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/ab7028438253/micromachines-15-01253-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/610d046e2b65/micromachines-15-01253-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/42d80c553378/micromachines-15-01253-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/3417b6fa7c75/micromachines-15-01253-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/7bfd2f288348/micromachines-15-01253-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/aae33fd5e764/micromachines-15-01253-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/be2e4cc4ff5c/micromachines-15-01253-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/933a2d3d9406/micromachines-15-01253-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5780/11509597/dcd6a8b3a6ff/micromachines-15-01253-g011.jpg

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本文引用的文献

1
Anodic Dissolution Characteristics of GH4169 Alloy in NaNO Solutions by Roll-Print Mask Electrochemical Machining Using the Linear Cathode.采用线性阴极的滚印掩膜电化学加工法研究GH4169合金在NaNO溶液中的阳极溶解特性。
Materials (Basel). 2024 Jun 4;17(11):2729. doi: 10.3390/ma17112729.
2
Experimental Characterization of Laser Trepanned Microholes in Superalloy GH4220 with Water-Based Assistance.水基辅助下高温合金GH4220激光打孔的实验表征
Micromachines (Basel). 2022 Dec 17;13(12):2249. doi: 10.3390/mi13122249.
3
Fabrication of micro pits based on megasonic assisted through-mask electrochemical micromachining.
基于兆声辅助掩膜电化学微加工的微孔制造。
Ultrasonics. 2020 Jan;100:105990. doi: 10.1016/j.ultras.2019.105990. Epub 2019 Aug 26.