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具有多种马来酰亚胺支架的光诱导转变

Photoinduced Transformations with Diverse Maleimide Scaffolds.

作者信息

Parthiban Jayachandran, Garg Dipti, Sivaguru Jayaraman

机构信息

Center for Photochemical Sciences, Department of Chemistry, Bowling Green State University, 141 Overman Hall, Bowling Green, OH 43403, USA.

出版信息

Molecules. 2024 Oct 16;29(20):4895. doi: 10.3390/molecules29204895.

Abstract

Maleimides serve as crucial components in various synthetic processes and are of significant interest to researchers in bioorganic chemistry and biotechnology. Although thermal reactions involving maleimides have been studied extensively, light-mediated reactions with maleimides remain relatively underutilized. This review focuses on understanding the behavior of maleimides in their excited state, particularly their role as synthetic scaffolds for excited-state reactions. Specific emphasis is placed on the diverse photoreactions involving maleimides and photophysical evaluation from our research group.

摘要

马来酰亚胺是各种合成过程中的关键成分,对生物有机化学和生物技术领域的研究人员具有重要意义。尽管涉及马来酰亚胺的热反应已得到广泛研究,但与马来酰亚胺的光介导反应仍未得到充分利用。本综述着重于了解马来酰亚胺在激发态下的行为,特别是它们作为激发态反应合成支架的作用。特别强调了我们研究小组涉及马来酰亚胺的各种光反应和光物理评估。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e385/11510057/d5d2f16a4c8c/molecules-29-04895-sch001.jpg

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