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用于研究陶瓷制造条件的离子束诱导发光(IBIL):在陶瓷地砖中的应用。

Ion Beam-Induced Luminescence (IBIL) for Studying Manufacturing Conditions in Ceramics: An Application to Ceramic Body Tiles.

作者信息

Corregidor Victoria, Ruvalcaba-Sil José Luis, Prudêncio Maria Isabel, Dias Maria Isabel, Alves Luís C

机构信息

Centro de Ciências e Tecnologias Nucleares, Instituto Superior Técnico, Campus Tecnológico e Nuclear, Universidade de Lisboa, E.N. 10 (km 139.7), 2695-066 Bobadela LRS, Portugal.

Instituto de Física, Universidad Nacional Autónoma de Mexico, Mexico City 04510, Mexico.

出版信息

Materials (Basel). 2024 Oct 17;17(20):5075. doi: 10.3390/ma17205075.

DOI:10.3390/ma17205075
PMID:39459780
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11509279/
Abstract

The first experimental results obtained by the ion beam-induced luminescence technique from the ceramic bodies of ancient tiles are reported in this work. The photon emission from the ceramic bodies is related to the starting minerals and the manufacturing conditions, particularly the firing temperature and cooling processes. Moreover, the results indicate that this non-destructive technique, performed under a helium-rich atmosphere instead of an in-vacuum setup and with acquisition times of only a few seconds, presents a promising alternative to traditional, often destructive, compositional characterisation methods. Additionally, by adding other ion beam-based techniques such as PIXE (Particle-Induced X-ray Emission) and PIGE (Particle-Induced Gamma-ray Emission), compositional information from light elements such as Na can also be inferred, helping to also identify the raw materials used.

摘要

本文报道了通过离子束诱导发光技术从古代瓷砖陶瓷体获得的首批实验结果。陶瓷体发出的光子与起始矿物和制造条件有关,特别是烧制温度和冷却过程。此外,结果表明,这种无损技术在富氦气氛而非真空环境下进行,采集时间仅需几秒,是传统的、通常具有破坏性的成分表征方法的一种有前景的替代方案。此外,通过添加其他基于离子束的技术,如粒子诱导X射线发射(PIXE)和粒子诱导γ射线发射(PIGE),还可以推断出诸如钠等轻元素的成分信息,有助于识别所使用的原材料。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/4ed8f5f5a9e1/materials-17-05075-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/985a274aeb80/materials-17-05075-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/dce3d61af914/materials-17-05075-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/35d9ae127e72/materials-17-05075-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/e7fe5f551d96/materials-17-05075-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/43bd7f20a2a1/materials-17-05075-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/4ed8f5f5a9e1/materials-17-05075-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/985a274aeb80/materials-17-05075-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/dce3d61af914/materials-17-05075-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/35d9ae127e72/materials-17-05075-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/e7fe5f551d96/materials-17-05075-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/43bd7f20a2a1/materials-17-05075-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/45e0/11509279/4ed8f5f5a9e1/materials-17-05075-g006.jpg

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本文引用的文献

1
LABEC, the INFN ion beam laboratory of nuclear techniques for environment and cultural heritage.LABEC,即国家核物理研究所用于环境与文化遗产的离子束核技术实验室。
Eur Phys J Plus. 2021;136(4):472. doi: 10.1140/epjp/s13360-021-01411-1. Epub 2021 Apr 30.
2
Non-Destructive Micro-Chemical and Micro-Luminescence Characterization of Jadeite.翡翠的无损微化学与微发光表征
Microsc Microanal. 2016 Dec;22(6):1304-1315. doi: 10.1017/S1431927616012010.
3
Application of cathodoluminescence microscopy and spectroscopy in geosciences.在地球科学中的应用阴极发光显微镜和光谱学。
Microsc Microanal. 2012 Dec;18(6):1270-84. doi: 10.1017/S1431927612001122. Epub 2012 Nov 15.
4
Multitechnique characterization of lapis lazuli for provenance study.采用多种技术对青金石进行产地研究的特征分析。
Anal Bioanal Chem. 2009 Dec;395(7):2211-7. doi: 10.1007/s00216-009-3039-7.
5
Some new trends in the ionoluminescence of minerals.矿物离子发光的一些新趋势。
Anal Bioanal Chem. 2007 Feb;387(3):869-78. doi: 10.1007/s00216-006-0798-2. Epub 2006 Oct 3.