Zhou Baocang, Zhao Zhihua, Lv Zhenli, Chen Zhuo, Kang Sibo
College of Mechanical and Electrical Engineering, Henan University of Technology, Zhengzhou 450052, China.
Sensors (Basel). 2024 Oct 10;24(20):6514. doi: 10.3390/s24206514.
The MXene TiCT was synthesized using hydrofluoric acid and an improved multilayer method in this study. Subsequently, a BiO/TiC2T composite material was produced through hydrothermal synthesis. This composite boasts a unique layered structure, offering a large surface area that provides numerous contact and reaction sites, facilitating the adsorption of ammonia on its surface. The prepared BiO/TiCT-based sensor exhibits excellent sensing performance for ammonia gas, including high responsiveness, good repeatability, and rapid response-recovery time. The sensor's response to 100 ppm ammonia gas is 61%, which is 11.3 times and 1.6 times the response values of the TiCT gas sensor and BiO gas sensor, with response/recovery times of 61 s/164 s at room temperature, respectively. Additionally, the gas sensitivity mechanism of the BiO/TiCT-based sensor was analyzed, and the gas sensing response mechanism was proposed. This study shows that the sensor can effectively enhance the accuracy and precision of ammonia detection at room temperature and has a wide range of application scenarios.
在本研究中,采用氢氟酸和改进的多层方法合成了MXene TiCT。随后,通过水热合成制备了BiO/TiC2T复合材料。这种复合材料具有独特的层状结构,拥有较大的表面积,提供了大量的接触和反应位点,便于氨在其表面的吸附。制备的基于BiO/TiCT的传感器对氨气表现出优异的传感性能,包括高响应性、良好的重复性和快速的响应-恢复时间。该传感器对100 ppm氨气的响应为61%,分别是TiCT气体传感器和BiO气体传感器响应值的11.3倍和1.6倍,在室温下的响应/恢复时间分别为61 s/164 s。此外,分析了基于BiO/TiCT的传感器的气敏机理,并提出了气敏响应机制。本研究表明,该传感器能够在室温下有效提高氨气检测的准确性和精度,具有广泛的应用场景。