二氨基卡宾衍生的钯和镍硫簇合物。
Diamidocarbene-derived palladium and nickel-sulfur clusters.
作者信息
Lee Minji, Noh Hyunju, Kim Youngsuk
机构信息
Department of Chemistry, Pusan National University, Busan, Republic of Korea.
Institute for Future Earth, Pusan National University, Busan, Republic of Korea.
出版信息
Chem Commun (Camb). 2024 Nov 21;60(94):13867-13870. doi: 10.1039/d4cc04582c.
PMID:39463347
Abstract
Novel palladium and nickel-sulfur clusters were synthesized using a diamidocarbene-derived carbon disulfide ligand. Structural characterization revealed a tetranuclear metal-sulfur cluster geometry with each metal center exhibiting square-planar coordination. The ligand was redox-active, accommodating oxidation states ranging from 0 to -2.
摘要
使用二氨基卡宾衍生的二硫化碳配体合成了新型钯和镍硫簇。结构表征揭示了一种四核金属硫簇几何结构，每个金属中心呈现平面正方形配位。该配体具有氧化还原活性，可容纳从0到-2的氧化态。
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