• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

基于金属有机框架和共价有机框架的气凝胶：合成、功能及应用

Metal-Organic Framework and Covalent-Organic Framework-Based Aerogels: Synthesis, Functionality, and Applications.

作者信息

Shao Gaofeng, Huang Xiaogu, Shen Xiaodong, Li Changxia, Thomas Arne

机构信息

School of Chemistry and Materials Science, Jiangsu Key Laboratory of New Energy Devices and Interface Science, Nanjing University of Information Science and Technology, Nanjing, 210044, China.

College of Materials Science and Engineering, Nanjing Tech University, Nanjing, 211816, China.

出版信息

Adv Sci (Weinh). 2024 Dec;11(48):e2409290. doi: 10.1002/advs.202409290. Epub 2024 Oct 28.

DOI:10.1002/advs.202409290
PMID:39467257
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC11672323/
Abstract

Metal-organic frameworks (MOFs) and covalent-organic frameworks (COFs)-based aerogels are garnering significant attention owing to their unique chemical and structural properties. These materials harmoniously combine the advantages of MOFs and COFs-such as high surface area, customizable porosity, and varied chemical functionality-with the lightweight and structured porosity characteristic of aerogels. This combination opens up new avenues for advanced applications in fields where material efficiency and enhanced functionality are critical. This review provides a comparative overview of the synthetic strategies utilized to produce pristine MOF/COF aerogels as well as MOF/COF-based hybrid aerogels, which are functionalized with molecular precursors and nanoscale materials. The versatility of these aerogels positions them as promising candidates for addressing complex challenges in environmental remediation, energy storage and conversion, sustainable water-energy technologies, and chemical separations. Furthermore, this study discusses the current challenges and future prospects related to the synthesis techniques and applications of MOF/COF aerogels.

摘要

基于金属有机框架（MOF）和共价有机框架（COF）的气凝胶因其独特的化学和结构性质而备受关注。这些材料将MOF和COF的优势——如高比表面积、可定制的孔隙率和多样的化学功能——与气凝胶的轻质和结构化孔隙率特性完美结合。这种结合为材料效率和功能增强至关重要的领域中的先进应用开辟了新途径。本综述对用于制备原始MOF/COF气凝胶以及用分子前驱体和纳米材料功能化的基于MOF/COF的混合气凝胶的合成策略进行了比较概述。这些气凝胶的多功能性使其成为应对环境修复、能量存储与转换、可持续水能源技术和化学分离等复杂挑战的有前途的候选材料。此外，本研究讨论了与MOF/COF气凝胶的合成技术和应用相关的当前挑战和未来前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/d93c9268c0e2/ADVS-11-2409290-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/d9de52fcafcd/ADVS-11-2409290-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/060716000eef/ADVS-11-2409290-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/8c7f62cc94f9/ADVS-11-2409290-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/b12a788c4f69/ADVS-11-2409290-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/91c6ae1f2f18/ADVS-11-2409290-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/bc31ca01ee02/ADVS-11-2409290-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/a866572849a9/ADVS-11-2409290-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/1d9871306b7f/ADVS-11-2409290-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/ace63ef70c6a/ADVS-11-2409290-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/b5a1858090ee/ADVS-11-2409290-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/5016875d609d/ADVS-11-2409290-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/6acd67a19cea/ADVS-11-2409290-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/efab31893f8b/ADVS-11-2409290-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/e02a70a29792/ADVS-11-2409290-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/5b21f98bb3f2/ADVS-11-2409290-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/4ca5819cf2c3/ADVS-11-2409290-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/c45b405be2c6/ADVS-11-2409290-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/9a628d8efaf4/ADVS-11-2409290-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/364ab12ca7f3/ADVS-11-2409290-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/53febdc5f749/ADVS-11-2409290-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/c54f2716d5d3/ADVS-11-2409290-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/17cc54ae243b/ADVS-11-2409290-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/37245c2d1d43/ADVS-11-2409290-g026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/d93c9268c0e2/ADVS-11-2409290-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/d9de52fcafcd/ADVS-11-2409290-g022.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/060716000eef/ADVS-11-2409290-g013.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/8c7f62cc94f9/ADVS-11-2409290-g019.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/b12a788c4f69/ADVS-11-2409290-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/91c6ae1f2f18/ADVS-11-2409290-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/bc31ca01ee02/ADVS-11-2409290-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/a866572849a9/ADVS-11-2409290-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/1d9871306b7f/ADVS-11-2409290-g023.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/ace63ef70c6a/ADVS-11-2409290-g029.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/b5a1858090ee/ADVS-11-2409290-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/5016875d609d/ADVS-11-2409290-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/6acd67a19cea/ADVS-11-2409290-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/efab31893f8b/ADVS-11-2409290-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/e02a70a29792/ADVS-11-2409290-g021.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/5b21f98bb3f2/ADVS-11-2409290-g028.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/4ca5819cf2c3/ADVS-11-2409290-g020.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/c45b405be2c6/ADVS-11-2409290-g014.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/9a628d8efaf4/ADVS-11-2409290-g027.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/364ab12ca7f3/ADVS-11-2409290-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/53febdc5f749/ADVS-11-2409290-g018.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/c54f2716d5d3/ADVS-11-2409290-g015.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/17cc54ae243b/ADVS-11-2409290-g024.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/37245c2d1d43/ADVS-11-2409290-g026.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8c4e/11672323/d93c9268c0e2/ADVS-11-2409290-g008.jpg

相似文献

1
Metal-Organic Framework and Covalent-Organic Framework-Based Aerogels: Synthesis, Functionality, and Applications.基于金属有机框架和共价有机框架的气凝胶：合成、功能及应用
Adv Sci (Weinh). 2024 Dec;11(48):e2409290. doi: 10.1002/advs.202409290. Epub 2024 Oct 28.
2
Process of metal-organic framework (MOF)/covalent-organic framework (COF) hybrids-based derivatives and their applications on energy transfer and storage.基于金属有机框架（MOF）/共价有机框架（COF）杂化物的衍生物的制备过程及其在能量转移与存储中的应用。
Nanoscale. 2022 Feb 3;14(5):1679-1699. doi: 10.1039/d1nr07614k.
3
Progress in Hybridization of Covalent Organic Frameworks and Metal-Organic Frameworks.共价有机框架和金属有机框架的杂交进展。
Small. 2022 Sep;18(38):e2202928. doi: 10.1002/smll.202202928. Epub 2022 Aug 19.
4
Covalent Metal-Organic Frameworks: Fusion of Covalent Organic Frameworks and Metal-Organic Frameworks.共价金属有机框架：共价有机框架与金属有机框架的融合
Acc Chem Res. 2025 Mar 4;58(5):746-761. doi: 10.1021/acs.accounts.4c00774. Epub 2025 Feb 21.
5
[Recent progress in magnetic covalent organic framework materials for the enrichment and detection of typical organic pollutants].用于典型有机污染物富集与检测的磁性共价有机框架材料的研究进展
Se Pu. 2025 Feb;43(2):107-119. doi: 10.3724/SP.J.1123.2024.07020.
6
[Research progress on preparation and applications of covalent organic framework-based chromatographic stationary phases].基于共价有机框架的色谱固定相的制备及应用研究进展
Se Pu. 2023 Oct;41(10):843-852. doi: 10.3724/SP.J.1123.2023.04021.
7
Quantum Capacitance through Molecular Infiltration of 7,7,8,8-Tetracyanoquinodimethane in Metal-Organic Framework/Covalent Organic Framework Hybrids.通过7,7,8,8-四氰基对苯二醌二甲烷分子渗透到金属有机框架/共价有机框架杂化材料中的量子电容
ACS Nano. 2021 Nov 23;15(11):18580-18589. doi: 10.1021/acsnano.1c09146. Epub 2021 Nov 12.
8
Metal-organic framework (MOF)/C-dots and covalent organic framework (COF)/C-dots hybrid nanocomposites: Fabrications and applications in sensing, medical, environmental, and energy sectors.金属有机框架（MOF）/碳点和共价有机框架（COF）/碳点杂化纳米复合材料：制备及其在传感、医学、环境和能源领域的应用
Adv Colloid Interface Sci. 2024 Jun;328:103178. doi: 10.1016/j.cis.2024.103178. Epub 2024 May 8.
9
[Synthesis of porous organic framework materials based on deep eutectic solvents and their application in solid-phase extraction].基于低共熔溶剂的多孔有机骨架材料的合成及其在固相萃取中的应用
Se Pu. 2023 Oct;41(10):901-910. doi: 10.3724/SP.J.1123.2023.08025.
10
Design of High-Performance Formyl-Functionalized COF Aerogels as Quasi-Solid Lithium Battery Electrolyte by a Solvent Substitution Strategy.通过溶剂置换策略设计高性能甲酰基功能化共价有机框架气凝胶作为准固态锂电池电解质
ACS Appl Mater Interfaces. 2024 Jul 17;16(28):37052-37062. doi: 10.1021/acsami.4c07017. Epub 2024 Jul 4.

引用本文的文献

1
Development of a Bio-Inspired Aerogel with Robust Sustainability and Thermal Insulation Performance.具有强大可持续性和隔热性能的仿生气凝胶的开发。
Materials (Basel). 2025 Jun 15;18(12):2808. doi: 10.3390/ma18122808.
2
Fe Wire-Based Metal-Organic Frameworks for Advanced Gas and Vapor Adsorption: Effect of Functional Compatibility on Hierarchical Pore Diffusivity and Atomic Simulation Insights.用于先进气体和蒸汽吸附的铁基金属有机框架：功能兼容性对分级孔扩散率的影响及原子模拟见解
ACS Appl Mater Interfaces. 2025 Jul 2;17(26):38597-38607. doi: 10.1021/acsami.5c04437. Epub 2025 May 18.
3
Data-Driven Review on Aerogels and Polymeric Aerogels.

本文引用的文献

1
Preparation of sp carbon-bonded π-conjugated COF aerogels by ultrasound-assisted mild solvothermal reaction for multi-functional applications.通过超声辅助温和溶剂热反应制备用于多功能应用的sp碳键合π共轭COF气凝胶。
Nanoscale. 2024 Aug 15;16(32):15298-15307. doi: 10.1039/d4nr02017k.
2
A photoluminescent hydrogen-bonded biomass aerogel for sustainable radiative cooling.用于可持续辐射冷却的光致发光氢键生物质气凝胶。
Science. 2024 Jul 5;385(6704):68-74. doi: 10.1126/science.adn5694. Epub 2024 Jul 4.
3
Ultralight and Robust Covalent Organic Framework Fiber Aerogels.
气凝胶和聚合物气凝胶的数据驱动综述
Angew Chem Int Ed Engl. 2025 Jul 7;64(28):e202504250. doi: 10.1002/anie.202504250. Epub 2025 Jun 5.
4
A Universal Approach to Anchoring Chromophores onto Magnetic Scaffold for Achieving Easily Recyclable Heterogeneous Photocatalytic Systems.一种将发色团锚定到磁性支架上以实现易于回收的多相光催化体系的通用方法。
Adv Sci (Weinh). 2025 Jul;12(26):e2502342. doi: 10.1002/advs.202502342. Epub 2025 Mar 26.
5
Advanced Solid Lubrication with COK-47: Mechanistic Insights on the Role of Water and Performance Evaluation.采用COK-47的先进固体润滑：关于水的作用的机理见解及性能评估
Adv Sci (Weinh). 2025 May;12(17):e2415268. doi: 10.1002/advs.202415268. Epub 2025 Jan 13.
超轻且坚固的共价有机框架纤维气凝胶
Small. 2024 Aug;20(32):e2311881. doi: 10.1002/smll.202311881. Epub 2024 Feb 19.
4
A generative artificial intelligence framework based on a molecular diffusion model for the design of metal-organic frameworks for carbon capture.一种基于分子扩散模型的生成式人工智能框架，用于设计用于碳捕获的金属有机框架。
Commun Chem. 2024 Feb 14;7(1):21. doi: 10.1038/s42004-023-01090-2.
5
Ultralight crystalline hybrid composite material for highly efficient sequestration of radioiodine.用于高效封存放射性碘的超轻晶体混合复合材料。
Nat Commun. 2024 Feb 10;15(1):1278. doi: 10.1038/s41467-024-45581-9.
6
Highly efficient removal of tetracyclines from water by a superelastic MOF-based aerogel: Mechanism quantitative analysis and dynamic adsorption.基于超弹性金属有机框架的气凝胶高效去除水中四环素：机理定量分析与动态吸附
J Environ Manage. 2024 Feb 27;353:120169. doi: 10.1016/j.jenvman.2024.120169. Epub 2024 Jan 29.
7
Cellulose acetate-based electrospun nanofiber aerogel with excellent resilience and hydrophobicity for efficient removal of drug residues and oil contaminations from wastewater.基于醋酸纤维素的静电纺纳米纤维气凝胶，具有优异的弹性和疏水性，可有效去除废水中的药物残留和油污。
Carbohydr Polym. 2024 Apr 1;329:121794. doi: 10.1016/j.carbpol.2024.121794. Epub 2024 Jan 9.
8
Efficient adsorption of radioactive iodine by covalent organic framework/chitosan aerogel.共价有机框架/壳聚糖气凝胶对放射性碘的高效吸附。
Int J Biol Macromol. 2024 Mar;260(Pt 2):129690. doi: 10.1016/j.ijbiomac.2024.129690. Epub 2024 Jan 23.
9
In situ growth of Zr-based metal-organic frameworks on cellulose sponges for Hg and methylene blue removal.基于锆的金属有机框架在纤维素海绵上原位生长用于去除汞和亚甲基蓝
Carbohydr Polym. 2024 Mar 15;328:121750. doi: 10.1016/j.carbpol.2023.121750. Epub 2023 Dec 30.
10
Proton-Conductive COF Evenly Embedded Cellulose Aerogels toward Water Harvesting and Spontaneous Sustained Power Generation from Ambient Moisture and Human Respiration.质子传导 COF 均匀嵌入纤维素气凝胶实现从环境湿度和人体呼吸中采集水和自发持续发电
ACS Appl Mater Interfaces. 2024 Jan 24;16(3):3279-3288. doi: 10.1021/acsami.3c14264. Epub 2024 Jan 10.